Advanced oxidation comprises a range of similar but different chemical processes aimed at tackling pollution in water, air and soil. Over the past few decades, multidisciplinary research has been carried out to study a broad spectrum of topics such as understanding of process fundamentals, elucidation of kinetics and mechanisms, development of new materials, modelling, process integration and scale-up. This article identifies and discusses certain directions that seem to advance R&D on advanced oxidation for water/wastewater treatment.
The electrochemical mineralization of organic pollutants is a new technology for treatment of dilute wastewater (COD < 5 g L -1 ). In this method, use of the electrical energy can produce complete oxidation of pollutants on high oxidation power anodes. An ideal anode for this type of treatment is a boron-doped diamond electrode (BDD) characterized by a high reactivity towards oxidation of organics. In the present work kinetic aspects of organic mineralization is discussed. The proposed theoretical kinetic model on boron-doped diamond anodes is in excellent agreement with experimental results. In addition economic aspects of electrochemical organic mineralization are reported.
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