Excessive livestock production in small areas poses a risk of nitrogen release to the environment and thus air and water contamination. Recovery of ammonia is necessary to avoid overfertilization, but manure management of untreated slurry is costly and complex. The authors discuss ammonium fertilizer recovery from manure using membrane processes and physicochemical methods including technology and energy assessments. Currently, nanofiltration, reverse osmosis, membrane distillation combined with ultrafiltration, and air stripping are the best choices. The processes rely highly on selection of appropriate pretreatment, as residual particulates will lead to fouling of membranes and stripping towers hence affect the performance greatly.
Over time fouling leads to membrane wetting. This is the biggest obstacle to widespread use of membrane distillation (MD) for ammonia removal from animal slurry. Feed pretreatment and cleaning strategies of membrane surfaces are the most common methods to prevent or diminish fouling phenomena. This study investigates preliminary fouling of polypropylene (PP), and polytetrafluoroethylene (PTFE) membranes. A model manure solution was used as feed. In addition, cleaning efficiencies with deionized water, NaOH/citric acid, and Novadan agents were studied. Further microfiltration and ultrafiltration were examined as manure pretreatment to diminish fouling. To this end polyvinylidene fluoride membranes (PVDF 0.2 µm and 150 kDa respectively) were used. Organic fouling was shown to be dominant. For the model manure solution, the fouling comprised lipids, carbohydrates and proteins. For pig slurry the fouling additionally contained carboxylates, free fatty acids and lignin. Among the tested cleaning strategies, Novadan agents were the most successful in removing proteins and carbohydrates from the PTFE membrane while it only removed proteins from the PP membrane. Using microfiltration or ultrafiltration as a pretreatment prior to MD doubled the ammonia mass transfer coefficient for the PTFE membrane, while for the PP membrane, the ammonia mass transfer coefficient was increased 4-fold.
Forward osmosis (FO) can be used to reclaim nutrients and high-quality water from wastewater streams. This could potentially contribute towards relieving global water scarcity. Here we investigated the feasibility of extracting water from four real and four synthetic anaerobically digested effluents, using FO membranes. The goal of this study was to 1) evaluate FO membrane performance in terms of water flux and nutrient rejection 2) examine the methane yield that can be achieved and 3) analyse FO membrane fouling. Out of the four tested real anaerobically digested effluents, swine manure and potato starch wastewater achieved the highest combined average FO water flux (>3 liter per square meter per hour (LMH) with 0.66 M MgCl as initial draw solution concentration) and methane yield (>300 mL CH per gram of organic waste expressed as volatile solids (VS)). Rejection of total ammonia nitrogen (TAN), total Kjeldahl nitrogen (TKN) and total phosphorous (TP) was high (up to 96.95%, 95.87% and 99.83%, respectively), resulting in low nutrient concentrations in the recovered water. Membrane autopsy revealed presence of organic and biological fouling on the FO membrane. However, no direct correlation between feed properties and methane yield and fouling potential was found, indicating that there is no inherent trade-off between high water flux and high methane production.
Large volumes of wastewater with dissolved wood components are treated in wastewater treatment plants at thermomechanical pulp mills. It has been shown previously that hemicelluloses in these wastewater streams can be recovered by membrane filtration. A serious obstacle when treating lignocellulose process streams is fouling of the membranes. Fouling not only increases operating costs but also reduces the operating time of the membrane plant. When optimizing the membrane cleaning method, it is important to know which compounds cause the fouling. In this work fouling of an ultrafiltration membrane was studied. The fouling propensity of untreated process water and microfiltrated process water was compared. Fouled membranes were analyzed using scanning electron microscopy and attenuated total reflection Fourier transform infrared spectrometry. Acid hydrolysis of membranes exposed to untreated process water and microfiltration permeate revealed that 508 mg/m 2 and 37 mg/m 2 of polysaccharides, respectively, remained on the membranes even after alkaline cleaning.
Forward osmosis (FO) is a low energy-intensive process since the driving force for water transport is the osmotic pressure difference, Δπ, between the feed and draw solutions, separated by the FO membrane, where π > π. The potential of FO in wastewater treatment and desalination have been extensively studied; however, regeneration of the draw solution (thereby generating clean water) requires application of an energy-intensive process step like reverse osmosis (RO). In this study, the potential of applying FO for direct water recirculation from diluted fermentation effluent to concentrated feedstock, without the need for an energy-intensive regeneration step (e.g. RO), has been investigated. Butanol production during crude glycerol fermentation by Clostridium pasteurianum, has been selected as a model process and the effect of cross-flow velocity and the dilution of draw solution on the water flux during short-term experiments (200 min), were investigated. Statistical analysis revealed that the dilution of the draw solution is the most influential factor for the water flux. Subsequent modelling of an integrated FO-fermentation process, showed that water recoveries could lead to substantial financial benefits, although the integrated FO-fermentation process demonstrated lower water flux than expected. FTIR analyses of the membrane surface implied that the decrease in water flux was due to the presence of proteins, polysaccharides and other extracellular polymeric substances on the membrane active layer, indicating the presence of a fouling layer. Based on these findings, possible fouling alleviation strategies and future research directions are discussed and proposed.
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