The synthesis and characterisation of the nonsymmetric liquid crystal dimer, 1-(4-cyanobiphenyl-4'-yloxy)-6-(4-cyanobiphenyl-4'-yl)hexane (CB6OCB) is reported. An enantiotropic nematic (N)-twist-bend nematic (NTB) phase transition is observed at 109 °C and a nematic-isotropic phase transition at 153 °C. The NTB phase assignment has been confirmed using polarised light microscopy, freeze fracture transmission electron microscopy (FFTEM), (2)H-NMR spectroscopy, and X-ray diffraction. The effective molecular length in both the NTB and N phases indicates a locally intercalated arrangement of the molecules, and the helicoidal pitch length in the NTB phase is estimated to be 8.9 nm. The surface anchoring properties of CB6OCB on a number of aligning layers is reported. A Landau model is applied to describe high-resolution heat capacity measurements in the vicinity of the NTB-N phase transition. Both the theory and heat capacity measurements agree with a very weak first-order phase transition. A complementary extended molecular field theory was found to be in suggestive accord with the (2)H-NMR studies of CB6OCB-d2, and those already known for CB7CB-d4. These include the reduced transition temperature, TNTBN/TNI, the order parameter of the mesogenic arms in the N phase close to the NTB-N transition, and the order parameter with respect to the helix axis which is related to the conical angle for the NTB phase.
A large aperture tunable lens based on liquid crystals, which is considered for near-to-eye applications, is designed, built, and characterized. Large liquid crystal lenses with high quality are limited by very slow switching speeds due to the large optical path difference (OPD) required. To reduce the switching time of the lens, the thickness is controlled through the application of several phase resets, similar to the design of a Fresnel lens. A main point of the paper is the design of the Fresnel structure to have a minimal effect on the image quality. Our modeling and experimental results demonstrate that minimal image degradation due to the phase resets is observable when the segment spacing is chosen by taking into account human eye resolution. Such lenses have applications related to presbyopia and, in virtual reality systems, to solve the well-known issue of accommodation-convergence mismatch.
Presbyopia is the failure of the eye lens to accommodate. The widely used presbyopia correction method involves wearing bi/trifocal or progressive glasses, which limits the field of view due to division of lens area into sections of different optical power. A large aperture focus tunable liquid crystal lens has the potential to correct human eye accommodation failure and provide a wide field of view. In this paper, we present characterization and demonstration of a segmented phase profile liquid crystal lens, which has the characteristics of a large area (diameter: 20 mm), being flat and thin (<2 mm), and having continuous focus tunability (1.5 D to 0 D), fast response time (<500 ms), low operating voltage (<5 V), and on-axis diffraction-limited performance (for a 5mm aperture). Considering all these properties, our lens provides performance details of an approach for presbyopia correction. We have tested the minimum resolution and visual acuity of 20 subjects using the designed lens and compared the results with a reference glass lens of the same optical power.
Vision discomfort due to the accommodation‐convergence mismatch remains a challenge for current HMDs used for VR/AR applications. A potential solution of this issue is to use an adaptive focus lens that is lightweight, flat and has a large aperture. In this paper, we present a 5 cm diameter Liquid Crystal based focus tunable lens. Despite the large aperture, the lens has characteristics of fast switching speed(500ms), low driving voltage (<5 V), and low thickness (<5mm).
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