The friction stir welding process is an innovative technique for joining metals using plasticity, without presenting the fusion. It was first applied to aluminum alloys, for example copper, steel alloys, polymers and others. In this work the effects of the rotational speed, the speed of travel and the axial force of the tool were grouped in a mathematical model to quantify their influences on the weld seam. In this context and with of the experimental tests, the desired objective through this study is to describe the tensile strength of the cord resulting from this welding operation, for the qualification of this type of parts with an optimum adapted to a given application.
This study examined adsorption of anionic dye on four zeolitic materials incorporated (VS-1, CuZSM-5) and not incorporated into metals (S-1, ZSM-5). The adsorption of the bromothymol blue (BTB) dye on the four adsorbents was analysed using isotherm models Langmuir, Freundlich, and Temkin. Two kinetic models were also applied to study the adsorption process, pseudo-first order and pseudo-second order. The isothermal data showed good correlation. The kinetics of adsorption were better described by the pseudo-second order model. The results obtained indicate that the maximum percentage removal of the BTB dye was given by a purely non-incorporated silicic zeolite (S-1).
Purpose
The purpose of this paper is to synthesize Cr-ZSM-5 using hydrothermal synthesis in acidic fluoride medium and the investigation of its catalytic performance in heterogeneous oxidation of 2-mercaptobenzothiazole in the presence of H2O2.
Design/methodology/approach
The framework was characterized by chemical composition, FT-IR, UV-visible spectroscopy, N2 adsorption (BET), and diffraction x-ray (DRX). FT-IR spectroscopy shows the characteristic band of Si-O-Cr linkage around 960-990 cm−1 and bands around 688-690 and 627 cm−1, indicating the presence of extraframework chromium oxide. UV spectra show a shoulder around 244-257 and bands around 360-380 nm, assigning the tetrahedral coordinated environment in (O2−=Cr6+) − (Cr5+-O−1), charge transfer transition state (CT) of isolated Cr (VI) inside the structure of Cr-ZSM-5.
Findings
The catalytic degradation of 2-mercaptobenzothiazole by H2O2 heterogenous oxidation using catalyst Cr-ZSM-5 showed the formation of bis (benzothiazoyl) disulfide with 95 percent yield.
Originality/value
The application of this process in the environment (catalysis, adsorption, and degradation of organic compounds).
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