We use broad-band dielectric spectroscopy to investigate the spin-state dependence of electrical properties of the [Fe(Htrz) 2 (trz)](BF 4 ) spin crossover complex. We show that the Havriliak−Negami theory can fully describe the variation of the complex dielectric permittivity of the material across the pressure−temperature phase diagram. The analysis reveals three dielectric relaxation processes, which we attribute to electrode/interface polarization, dipole relaxation, and charge transport relaxation. The contribution of the latter appears significant to the dielectric strength. Remarkably, the permittivity and conductivity changes between the high spin and low spin states are amplified at the corresponding relaxation frequencies.

The water quality of rivers worldwide is of persistent interest due to its impact on human life. Five streamwater quality parameters of Suceava River were monitored in 2019 upstream and downstream of Suceava city, Romania: dissolved oxygen, specific conductivity, pH, oxidation-reduction potential, and temperature. Data was recorded at a high temporal frequency, every hour, and produced Water Quality Index (WQI) time series of similar resolution. Our additive WQI has variants with particular advantages. Water quality of Suceava city exhibits a diurnal cycle. Upstream, WQI values indicate a quasi-permanent good water quality; downstream, the water quality oscillates around the average WQI value because of the various sources of water contaminants, especially the wastewaters from the wastewater treatment plant. Parameters from this point source of pollution are taken into account to explain the decaying streamwater quality towards the end of 2019. WQI is useful for detecting time intervals when water self-purification events have a high chance of occurrence.

As fuel consumption in the transport sector has increased at a faster pace than in other sectors, the use of electromobility represents the main strategy adopted by the automotive industry. In this context, as the number of electrical vehicles (EVs) will increase, it will also be necessary to increase the number of charging stations. The present paper presents a complete solution for charging stations that can be located in the office or mall parking area. This solution includes a mode 3 AC charging stations of International Electrotechnical Commission (IEC) 61851-1 Standard, an EV simulator for testing the good functionality of the charging stations (i.e., communications, residual-current device (RCD) protection) and a software application used for controlling the charging process by the programmable logic controller (PLC).

Cities alter the thermal regime of urban rivers in very variable ways which are not yet deciphered for the territory of Romania. The urban heat island of Suceava city was measured in 2019 and its impact on Suceava River was assessed using hourly and daily values from a network of 12 water and air monitoring stations. In 2019, Suceava River water temperature was 11.54 °C upstream of Suceava city (Mihoveni) and 11.97 °C downstream (Tişăuţi)—a 3.7% increase in the water temperature downstream. After the stream water passes through the city, the diurnal thermal profile of Suceava River water temperature shows steeper slopes and earlier moments of the maximum and minimum temperatures than upstream because of the urban heat island. In an average day, an increase of water temperature with a maximum of 0.99 °C occurred downstream, partly explained by the 2.46 °C corresponding difference between the urban floodplain and the surrounding area. The stream water diurnal cycle has been shifted towards a variation specific to that of the local air temperature. The heat exchange between Suceava River and Suceava city is bidirectional. The stream water diurnal thermal cycle is statistically more significant downstream due to the heat transfer from the city into the river. This transfer occurs partly through urban tributaries which are 1.94 °C warmer than Suceava River upstream of Suceava city. The wavelet coherence analyses and ANCOVA (analysis of covariance) prove that there are significant (0.95 confidence level) causal relationships between the changes in Suceava River water temperature downstream and the fluctuations of the urban air temperature. The complex bidirectional heat transfer and the changes in the diurnal thermal profiles are important to be analysed in other urban systems in order to decipher in more detail the observed causal relationships.

There are numerous streamwater parameters that exhibit a diurnal cycle. However, the shape of this cycle has a huge variation from one parameter to another and from one monitoring point to another on the same river. Important variations also occur at the same point during some events, such as high waters. Water level, specific conductivity, dissolved oxygen, oxidation reduction potential, and pH of the Suceava River were monitored for 365 days (2018–2019, hourly sampling frequency) in order to assess the upstream-downstream changes in the diurnal cycle of these parameters, some of these changes being caused by the impact of Suceava city, which is located between the selected monitoring points. The multiresolution analysis of the maximal overlap discrete wavelet transform and the wavelet coherence analysis were combined in a flexible methodology that helped in comparing the upstream and downstream shapes of the diurnal cycle. The methodology allowed for a fast comparison of diurnal profiles during periods of high waters or baseflow. Notable changes were observed in the moments of diurnal maxima and minima.

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This paper proposes a new screening system for quantitative evaluation and analysis, designed for the early stage detection of Parkinson disease. This has been carried out in the view of improving the diagnosis currently established upon a basis of subjective scores. Parkinson?s disease (PD) appears as a result of dopamine loss, a chemical mediator that is responsible for the body?s ability to control movements. The symptoms reflect the loss of nerve cells, due to an unknown. The input parameters of the system are represented by amplitude, frequency, the spectral characteristic and trembling localization. The main symptoms include trembling of hand, arms, movement difficulties, postural instability, disturbance of coordination and equilibrium, sleep disturbance, difficulties in speaking, reducing of voice volume. The medical knowledge in PD field is characterized by imprecision, uncertainty and vagueness. The proposed system (fuzzy expert systems) is non-invasive and, easy to use by both physicians and patients at home

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