Every
year, millions of tons of CO2 are stored in CO2-storage formations (deep saline aquifers) containing traces
of organic acids including hexanoic acid C6 (HA), lauric
acid C12 (LuA), stearic acid C18 (SA), and lignoceric
acid C24 (LiA). The presence of these molecules in deep
saline aquifers is well documented in the literature; however, their
impact on the structural trapping capacity and thus on containment
security is not yet understood. In this study, we therefore investigate
as to how an increase in organic acid concentration can alter mica
water wettability through an extensive set of experiments. X-ray diffraction
(Figure S2), field emission scanning electron microscopy, total organic
carbon analysis, Fourier-transform infrared spectroscopy, atomic force
microscopy, and energy-dispersive X-ray spectroscopy were utilized
to perceive the variations in organic acid surface coverage with stepwise
organic acid concentration increase and changes in surface roughness.
Furthermore, thresholds of wettability that may indicate limits for
structural trapping potential (θr < 90°)
have been discussed. The experimental results show that even a minute
concentration (∼10–5 mol/L for structural
trapping) of lignoceric acid is enough to affect the CO2 trapping capacity at 323 K and 25 MPa. As higher concentrations
exist in deep saline aquifers, it is necessary to account for these
thresholds to derisk CO2-geological storage projects.
Geological H 2 storage plays a central role to enable the successful transition to the renewable H 2 economy and achieve net-zero emission in the atmosphere. Depleted oil and gas reservoirs are already explored with extensive reservoir and operational data. However, residual hydrocarbons can mix with injected H 2 in the reservoirs. Furthermore, low density and high diffusivity of H 2 may establish H 2 leakage from the reservoirs via fault pathways. Interestingly, H 2 can be consumed by microorganisms, which results in pore-network precipitation, plugging, and partial permeability impairment. Therefore, stored H 2 may be lost in the formations if the storage scenario is not planned cautiously. While salt caverns are safe and commercially proven geo-rock for H 2 storage, they have low-storage capacity compared to depleted gas reservoirs. Moreover, salt structures (e.g., domel, bedded) and microorganisms activities in the salt cavern are limiting factors, which can influence the storage process. Accordingly, we discuss challenges and future perspectives of hydrogen storage in different geological settings. We also highlight geographical limitations with diverse microbial communities and theoretical understanding of abiotic transformation (in terms of rock's minerals, i.e., mica and calcite) for geological H 2 storage. Regarding the fundamental behavior of H 2 in the geological settings, it is less soluble in formation water; therefore, it may achieve less solubility trapping compared to CO 2 and CH 4 . Furthermore, H 2 gas could attain higher capillary entrance pressures in porous media over CH 4 and CO 2 due to higher interfacial tension. Additionally, the low viscosity of H 2 may facilitate its injection and production but H 2 may establish the secondary trapping and viscous fingering. Thus, this review documents a blend of key information for the amendment of subsurface H 2 storage at the industrial scale.
The energy industry is exploring sustainable chemistry and engineering solutions for exploitation of shale reservoirs. Smectite-rich shale is challenging to drill with traditional water-based drilling fluid (WBDF). The objectives of this study are (i) to investigate acute toxicity of drilling fluids and (ii) to enhance the rheological properties, lubricity, and clay inhibition behavior of WBDF by adding Tween 80 (T80)/ZnO nanoparticles. Acute toxicity results revealed 100% survival rate of white leg shrimp in WBDF waste. At 0.7 g, the optimum concentration of T80ZnO, the plastic viscosity (PV) was improved by 12%; the negative surface charge of nanomaterial might have improved repulsion forces/stability and enhanced viscosity in the drilling fluids. Yield point (YP) was improved by 71%, moreover 10 min gel strength (GS) and 10 s GS were significantly increased by 32 and 54%, respectively. The metal oxide nanosolids induced heat transfer characteristics and ensured gelling and yield strength properties. Lubricity was slightly increased by 7%; the ZnO nanorods between the two sliding contact surfaces (i.e., assuming drill pipe and casing) improved lubricity. Filtrate loss (FL) volume was considerably minimized to 17 and 30% at API and high-pressure, high-temperature (HPHT) conditions, respectively; this observation could be explained by pores plugging in the filter paper. Heated clay swelling inhibition was optimized after addition of 0.6 g of T80ZnO nanoparticles to WBDF. The clay inhibition was enhanced by 9 and 17% when compared to conventional WBDF and fresh water, respectively; this progress might have attributed to the corresponding: (i) pores plugging in the clay and (ii) interparticle pores bridging between existing drilling additives and nanomaterial. The above findings identify that this drilling fluid could attain sustainable environmental and operational success while drilling into montmorillonite/smectite rich-clay and shale rock.
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