Reverse electrodialysis (RED) represents one of the most promising membrane-based technologies for clean and renewable energy production from mixing water solutions. However, the presence of multivalent ions in natural water drastically reduces system performance, in particular, the open-circuit voltage (OCV) and the output power. This effect is largely described by the “uphill transport” phenomenon, in which multivalent ions are transported against the concentration gradient. In this work, recent advances in the investigation of the impact of multivalent ions on power generation by RED are systematically reviewed along with possible strategies to overcome this challenge. In particular, the use of monovalent ion-selective membranes represents a promising alternative to reduce the negative impact of multivalent ions given the availability of low-cost materials and an easy route of membrane synthesis. A thorough assessment of the materials and methodologies used to prepare monovalent selective ion exchange membranes (both cation and anion exchange membranes) for applications in (reverse) electrodialysis is performed. Moreover, transport mechanisms under conditions of extreme salinity gradient are analyzed and compared for a better understanding of the design criteria. The ultimate goal of the present work is to propose a prospective research direction on the development of new membrane materials for effective implementation of RED under natural feed conditions.
Ethiopia is one of the fastest-growing economies in the world despite immense challenges towards access to sustainable energy supplies and modern energy technologies. The country is undertaking great effort towards the development of renewable energy technologies and green legacy. However, the largest share of energy consumption (≈87%) in Ethiopia is dominated by traditional fuels (charcoal, fuel wood, dung cakes, and agricultural residues) which pose various health and environmental risks. The country has an enormous amount of renewable energy potentials (e.g., solar, hydro, wind and geothermal), but only 5% of its full hydropower potential is exploited and others are not fully harvested or not well developed to date. This review paper provides a comprehensive assessment on renewable energy availability, potential, opportunity, and challenges in Ethiopia. We believe the information provided in this review will enlighten the current and future prospects of renewable energy deployment in Ethiopia.
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