Copper(I) halide complexes are well sought-after materials due to their rich structural diversities and photophysical properties. Profoundly, there is a direct relationship between each structural variation and luminescence of these complexes, for a purported use. In this review, recent publications within the last 2 years about copper(I) halide complexes, centering on their structural dimensionalities with derivatives of nitrogen, phosphorus, and sulfur ligands, have been considered alongside their effects on luminescence.
Two novel Cadmium(II)‐based luminescent metal‐organic frameworks (LMOFs), namely, {[Cd(tipe)0.5(OBA)]⋅(H2O)5} [tipe=1,1,2,2‐tetrakis(4‐(1H‐imidazol‐1‐yl)phenyl)ethene, OBA=4,4‐oxoybis(benzoic acid)] (MOF‐1) and [Cd2(tipe)(SDC)2] (SDC=4,4′‐stilbenedicarboxylic acid) (MOF‐2), have been prepared by a tetraphenylethene (TPE)‐core ligand under hydrothermal condition. Results of single crystal X‐ray diffraction show that MOF‐1 crystallizes in monoclinic system and MOF‐2 crystallizes in the triclinic system. And two complexes all have blue emission with maximal peaks at 488 nm (MOF‐1) and 477 nm (MOF‐2), respectively. Solvent exchange experiments show that they are stable in most of organic solvents. As to MOF‐1, there exist different degrees of quenching or different stokes shifts in these solvents. It proves that MOF‐1 can have potential application in sensing organic solvents. Due to MOF‐2’s structural intercalation, the presence of organic solvents causes a large degree of quenching of fluorescence because they take part in photo‐induced electron transfer (PET) process.
Organic-inorganic hybrid materials have structural diversity and flexibility. The introduction of Sb(Ⅲ) metal ions in the inorganic part can bring about semiconductor performance. In this paper, we successfully adjusted the...
Four novel all-in-one structured cuprous iodide hybrid materials are presented. Isomerization of the alkyl chain on ligand improved materials thermal stability and regulated their luminescence to warm and near-white light...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.