In this study, the laboratory scale production of activated carbon synthesized from PVC with CoCl2 and H3PO4, which is cheaper and has a good yield source material, is reported.

In this work, solution cast method was adapted for the preparation of 1-ethyl-3-methylimidazolium dicyanamide (EMImDCN)-doped solid polymer electrolyte. Optimum composition of polymer electrolyte (polyethylene oxide + sodium iodide) was treated as the host polymer. The ionic conductivity was further enhanced by adding low-viscosity ionic liquid (IL) EMImDCN. Electrical, thermal, dielectric, and photoelectrochemical properties of polymer host and IL-doped solid polymer electrolyte (ILDPE) are presented in detail. An electrochemical device, that is, dye-sensitized solar cell was fabricated using maximum conducting ILDPE film, which shows short-circuit current density of 0.118 mA/cm2, open-circuit voltage of 0.71 V, and overall efficiency of 0.061% at 1 sun condition.

We have successfully synthesized highly conducting polymer electrolyte incorporated ionic liquid films. There was a rise in conductivity by ionic liquid doping which is clarified by impedance spectroscopy. Fourier transform infra red spectroscopy confirms complexation as well as composite nature. Polarized optical microscopy shows decrease in crysatllinity (more amorphous) by ionic liquid doping. Maximum conducting ionic liquid incorporated polymer electrolyte sandwitched between electrodes, used for fabricating electrical double layer capacitor (EDLC) and dye sensitized solar cell (DSSC) further affirm that these ionic liquid doped polymer electrolyte could be a novel alternative in electrochemical devices.

The present investigation deals with the preparation of multi-walled carbon nanotube (MWCNT)-doped plasticized polymer electrolyte. The nanocomposite has been prepared using solution casting method. Complex impedance spectroscopy study revealed the utmost room temperature conductivity of 5.6 × 10−4 S/cm when optimized plasticized polymer electrolyte (poly(ethyl methacrylate)+30% sodium iodide+60% ethylene carbonate) was doped with 7% MWCNT. Temperature dependence of conductivity showed Arrhenius behavior. The surface morphology and crystalline–amorphous deviation of the composite was observed using scanning electron microscope. Perfect complexation of various components of the composite was confirmed from Fourier-transform infrared spectroscopy and X-ray diffraction (XRD) data. The transference number measurement was done to calculate the proportionate amount of ionic and electronic conductivity. A dye sensitized solar cell has been fabricated using maximum ionic conductivity of solid polymer electrolyte and its electrical parameters measured at 1 sun condition.

Due to various useful properties of polyethers, the prime objective of present paper is to develop an efficient supercapacitor based on high conducting polymer electrolyte and carbon based materials. To develop such films Polyvinylidene fluoride co-hexafluoropropylene (PVDF-HFP) polymer doped with ionic liquid (IL) 1-ethyl-3-methylimidazolium thiocyanate has been prepared using solution cast technique. The detail studies of polymer electrolyte with optimized value of IL: PVDF-HFP i.e. (80:20) we have reported elsewhere. For electrodes, cobalt enriched porous carbon material has been synthesized and characterized in detail. A sandwiched type electric double layer supercapacitor (EDLC) has been fabricated using maximum conducting polymer-IL film which shows ultra-high capacitance of 294 F/g at room environmental condition. This work successfully demonstrates the suitability of polymer electrolyte in developing highly efficient energy devices.

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Solid polymer electrolyte films blended with ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide (EMImTCM) and poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) are prepared via solution cast technique. The physical characterization of polymeric film is performed by X-ray diffraction (XRD), polarized optical microscopy (POM), Fourier transform infrared spectroscopy (FTIR), and thermo-gravimetric analysis (TGA) studies. The gel electrolyte film with 300 wt% of IL shows the high ionic conductivity value of 3.7 Â 10 À2 S cm À1 , and operating voltage from À0.5 to 1.5 V, i.e., electrochemical stability window (ESW) % 2.0 V. The dielectric properties of the polymeric films such as dielectric constant, dielectric loss tangent (Tan δ), relaxation frequency, and time are evaluated.