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In the last years, a rising trend of pollen allergies in urban areas has been attributed to atmospheric pollution. In this work, we investigated the effects of SO(2) and NO(2) on the protein content, allergenicity, and germination rate of Acer negundo pollen. A novel environmental chamber was assembled to exposure pollen samples with SO(2) or NO(2) at two different levels: just below and two times the atmospheric hour-limit value acceptable for human health protection in Europe. Results showed that protein content was lower in SO(2)-exposed pollen samples and slightly higher in NO(2)-exposed pollen compared to the control sample. No different polypeptide profiles were revealed by SDS-PAGE between exposed and nonexposed pollen, but the immunodetection assays indicated higher IgE recognition by all sera of sensitized patients to Acer negundo pollen extracts in all exposed samples in comparison to the nonexposed samples. A decrease in the germination rate of exposed in contrast to nonexposed pollen was verified, which was more pronounced for NO(2)-exposed samples. Our results indicated that in urban areas, concentrations of SO(2) and NO(2) below the limits established for human protection can indirectly aggravate pollen allergy on predisposed individuals and affect plant reproduction.
The design of new advanced materials and technologies is essential for the development of smart windows for the next generation of energy-efficient buildings. Here, it is demonstrated that the functionalization of glucose-derived carbon dots with 1-butyl-3-methylimidazolium chloride results in a self-standing, water-soluble, viscous, reusable nanofluid with self-improving conductivity, thermotropy around 30-40 °C, and ultraviolet blocking ability. Its synthesis is straightforward, clean, fast, and cheap. At 36 °C (hot summer day), a sunactuated thermotropic (TT) device incorporating a 95% w/w nanofluid aqueous solution exhibits a transmittance variation (ΔT) of 9% at 550/1000 nm, which is amplified to 47/31% via the surface plasmon resonance effect. An integrated self-healing system enabling independent sun-actuated TT and voltage-actuated electrochromic (EC) operation is also produced. The low-energy EC device offers bright hot and dark cold modes (ΔT = 68/64%), excellent cycling stability, unprecedented coloration efficiency values (−1.73 × 10 6 /−1.67 × 10 6 cm 2 C −1 (coloring) and +1.12 × 10 7 /+1.08 × 10 7 cm 2 C −1 (bleaching) at ±2.5 V), and impressive memory effect. The disruptive design and sustainable synthesis of the new nanofluid proposed here will foster the agile development of novel products with improved ecological footprint.
O PDF relativo ao artigo que solicita, não se encontra disponível em Acesso Aberto.
Motivos: O editor não permite o depósito e disponibilização em acesso aberto do PDF que solicita. Para consultar o documento deve aceder ao endereço do editor.
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