Due to their potential applications in industry and potent toxicity to the environment, sulfides and their detection have attracted the attention of researchers. To date, a large number of controlled‐potential techniques for electrochemical sulfide sensors have been developed, thanks to their simplicity, reasonable limit of detection (LOD), and good selectivity. Different researchers have applied different strategies for developing selective and sensitive sulfide sensors. However, there has been no systematic review on controlled‐potential techniques for sulfide sensing. In light of this absence, the main aim of this review article is to summarize various strategies for detecting sulfide in different media. The efficiencies of the developed sulfide sensors for detecting sulfide in its various forms are determined, and the essential parameters, including sensing strategies, working electrodes, detection media, pH, LOD, sensitivity, and linear detection range, are emphasized in particular. Future research in this area is also recommended. It is expected that this review will act as a basis for further research on the fabrication of sulfide sensors for practical applications.
Nano-Co 3 O 4 was used for electrocatalytic water oxidation due to its promising features of better performance and low cost. An enhanced electrochemical water oxidation performance of the nanoparticles can be achieved by mixing them with other types of highly conductive nano/microstructured materials. Conductive polymers would be one of the candidates to achieve this goal. Here, we report our recently developed nano-Co 3 O 4 and polypyrrole composites for enhanced electrochemical water oxidation. We chose polypyrrole as a support of nano-Co 3 O 4 to obtain highly active sites of nano-Co 3 O 4 with high conductivity. Morphological and chemical characterization of the prepared materials were performed using scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). After immobilizing them individually on fluorine doped tin oxide (FTO) substrate, their electrocatalytic properties toward water oxidation were investigated. The optimum composite materials showed significantly higher electrocatalytic properties compared to that of pure nano-Co 3 O 4 and polypyrrole. Electrochemical impedance studies indicated that the composite materials possess significantly less electron transfer resistance toward water oxidation reaction compared to that of only polypyrrole or nano-Co 3 O 4 , while the higher double-layer capacitance and polarization resistance values obtained from fitting of the impedance data represent the faster electrode kinetics in the composite electrocatalyst. Due to the synergetic effect, the optimum nano-Co 3 O 4 and polypyrrole composites could be represent a novel and promising material for water oxidation.
A sulfide sensor based on an indium tin oxide nanoparticle (ITONP)‐modified ITO electrode was developed. To prepare ITONP‐modified ITO, various methods were tested. Drop‐drying of ITONPs (aq.) on aminopropyltrimethoxysilane‐functionalized ITO (APTMS/ITO) was found to be the best method on the basis of voltammetric analysis of the sulfide ion. ITONP‐modified APTMS/ITO (ITONP/APTMS/ITO) yielded much better electrocatalytic properties toward sulfide electro‐οxidation than did bare or APTMS/ITO electrodes. The ITONPs and ITONP‐modified ITO were also characterized using transmission electron microscopy and field emission scanning electron microscopy, respectively. Optimization of the type of inert electrolyte and pH yielded an ITONP/APTMS/ITO detector whose amperometrically and chronocoulοmetrically determined limits of detection for sulfide were 3.0 μM and 0.90 μM, respectively. ITONP/APTMS/ITO electrodes displayed reproducible performance, were highly stable, and were not susceptible to interference by common contaminants. Thus, the developed electrode can be considered as a promising tool for sensing sulfide.
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