We report here the unprecedented modification of the hydrogen absorption/desorption properties of 1 nm Pd clusters relative to the bulk and nanoparticles down to 2–3 nm.
Physisorption and chemisorption of hydrogen on solid-state materials are two fundamentally different interactions, both of which display advantages and drawbacks for hydrogen storage. It has been hypothesised that their combination by merging two classes of materials showing different sorption behaviour towards hydrogen in the same composite may synergistically combine their desirable properties. As representatives of such composites, palladium nanoparticles, nanoclusters, and single atoms have been encapsulated in a metal-organic framework matrix, embedded, or immobilised in its pores, respectively. In this minireview, we review advances on the understanding and potential applications of the combination of Pd with metalorganic framework matrices through the analysis of the nanocomposite materials' interaction with hydrogen and sorption properties.[a] Dr.
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