As the need for water is increasing in Palestine, and the available water resources are barely sufficient to meet the demands of the current quality of life and the economy, air conditioner condensate water could be explored as an alternative water source. The objective of this study is to better understand the potential for recovery of condensate water from air conditioning systems in two Palestinian cities. In addition, this study aims to evaluate this water source in terms of quality and quantity. Generally, it was found that the condensate water has good quality, which conforms to the Palestinian standards for reused water for irrigation, except for turbidity, biological oxygen demand (BOD) and chemical oxygen demand (COD) measurements. Reflecting the heavy metal occurrence in the collected condensate water, no particular risk was recognized for drinking water or reused irrigation standards, except for manganese occurrence of 0.19 mg/L in one sample. From a single unit capacity, high quantities of water were observed of approximately 259 L and 453 L per month in Ramallah and Jericho cities, respectively. These figures should draw the attention of decision and policy makers to put in place strict technical guidelines to be followed for potential reuse of condensate water at the local level.
A cellulose derivative with multiple coordination sites for metals composed of cellulose powder and 1,2-pheneylnediamine was synthesized and evaluated as an adsorbent for metal ions from wastewater. The cellulose powder was generated from the solid waste of the olive industry. The adsorption efficiency of the cellulose amine polymer toward Fe(III) and Pb(II) was investigated as a function of adsorbent dose, temperature, pH, and time. The adsorption parameters that lead to excellent adsorption efficiency were determined. In addition, the polymer showed an excellent extraction efficiency toward approximately 20 metal ions present in a sewage sample. The cellulose amine derivative had several coordination sites that included amine, hydroxyl, and aromatic groups. The diversity and frequency of the coordination sites explained the high efficiency of the polymer for metal ions. The thermodynamic analysis results supported the spontaneous adsorption efficiency of the polymer at room temperature. The adsorption process fit well with the Langmuir adsorption isotherm model.
Until relatively recently, little has been done of effective technique "zero effluent" to conserve energy and water. Tannery wastewater is known as complex characteristics. In this study batch electrocoagulation experiments were carried out to assess the removal of color and chemical oxygen demand (COD) from tannery wastewater using two types of electrode materials: aluminum and iron. The effects of current density, electrolysis time and initial pH were investigated for tannery wastewater. Therefore, the operating costs for each electrode have been calculated. Based on results, it can be concluded that iron is tremendous to aluminum as electrode material, from COD removal and energy consumption views. All the conclusions of the study revealed that treatment of tannery by EC can be applied as a step of a hybrid treatment.
In this work, we present a process for converting olive industry solid waste (OISW) into a value-added material with ionic receptors for use in the removal of toxic metal ions from wastewater. This 3D polymer is a promising adsorbent for large-scale application, since it is a low-cost material made from agricultural waste and showed exceptional performance. The synthesis of the network polymer involved the carboxymethylation of OISW and curing of the carboxymethylated OISW at an elevated temperature to promote the formation of ester linkages between OISW’s components. FT-IR, atomic force microscopy, and thermal analysis were performed on the crosslinked product. The adsorption efficiency of the crosslinked carboxymethylated OISW toward Pb(II), Cu(II), and other toxic metal ions present in sewage was evaluated as a function of adsorbent dose, temperature, pH, time, and initial metal ion. The percentage removal of about 20 metal ions present in a sewage sample collected from a sewer plant located in the Palestinian Territories was determined. The adsorption efficiency did not drop even after six cycles of use. The kinetic study showed that the adsorption process follows the Langmuir isotherm model and the second-order adsorption rate. The experimental Qe values of 13.91 and 13.71 mg/g were obtained for Pb(II) and Cu(II) removal, respectively. The thermodynamic results confirm the spontaneous metal bonding to the receptor sites of the crosslinked carboxymethylated OISW.
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