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Thermoelectric or Seebeck effect devices are beginning to see wide-spread use in metal and alloy sorting and verification processes, prompting the recent approval of ASTM Practice for Thermo-electric Sorting of Electrically Conductive Materials (E 977). This paper briefly explores the history of its use and discusses the theory of the method, while focusing deeper attention on practical applications of the devices and areas of its limitations. Testing requirements, specific material separations and examples, variables, advantages, disadvantages, and traceability are highlighted.
Volume I in this series deals with organic chemicals that fall into the category of large production volumes and priority pollutants. This reference work is well organized and easy to follow. It provides not only data but a brief discussion of particular topics such as log octanol/water partition coefficient, biodegradation, abiotic degradation, and bioconcentration. The author's description of each of these topics extremely helpful, especially to those using these types of data for the first time. However, all terms used in these sections are not defined. While there are some minor differences in some physical data between this and other reference books, the author supplies the reference with the data, allowing one to easily find the original source. It is also important to realize that, while this is a good reference book, for fate and exposure data, no aquatic toxicity data are listed.
This paper discusses design of vapor cleaning systems and how proper design can reduce solvent losses from these units. It addresses such items as proper freeboard, work openings, heat balance, compartment dimensions, covers, operational controls, and heating elements. Solvent loss mechanisms are discussed in detail, such as diffusional losses, solvent drag-out, leakage, and poor maintenance. One section is devoted to choosing the proper solvent for a cleaning system and how the physical characteristics of solvents can contribute to high losses if the solvent is improperly chosen. Solvent emission reduction devices, such as hoods, transport systems, freeboard chillers, containment of sprays, hot vapor drying, carbon adsorbers, and solvent cool-down coils, are detailed in regard to their effectiveness. The final section is dedicated to process control of the cleaning system through the use of computers.
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