-hexafluoropropane). In situ measurements are from the global monitoring sites of the Advanced Global Atmospheric Gases Experiment (AGAGE), the System for Observations of Halogenated Greenhouse Gases in Europe (SOGE), and Gosan (South Korea). We include the first halocarbon flask sample measurements from the Antarctic research stations King Sejong and Troll. We also present measurements of archived air samples from both hemispheres back to the 1970s. We use a two-dimensional atmospheric transport model to simulate global atmospheric abundances and to estimate global emissions. HFC-365mfc and HFC-245fa first appeared in the atmosphere only ∼1 decade ago; they have grown rapidly to globally averaged dry air mole fractions of 0.53 ppt (in parts per trillion, 10 −12 ) and 1.1 ppt, respectively, by the end of 2010. In contrast, HFC-227ea first appeared in the global atmosphere in the 1980s and has since grown to ∼0.58 ppt. We report the first measurements of HFC-236fa in the atmosphere. This long-lived compound was present in the atmosphere at only 0.074 ppt in 2010. All four substances exhibit yearly growth rates of >8% yr −1 at the end of 2010. We find rapidly increasing emissions for the foam-blowing compounds HFC-365mfc and HFC-245fa starting in ∼2002. After peaking in 2006 (HFC-365mfc: 3.2 kt yr −1 , HFC-245fa: 6.5 kt yr −1 ), emissions began to decline. Our results for these two compounds suggest that recent estimates from long-term projections (to the late 21st century) have strongly overestimated emissions for the early years of the projections (∼2005-2010). Global HFC-227ea and HFC-236fa emissions have grown to average values of 2.4 kt yr −1 and 0.18 kt yr −1 over the 2008-2010 period, respectively.

Abstract. Atmospheric hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs) were measured in-situ at the Shangdianzi (SDZ) Global Atmosphere Watch (GAW) regional background station, China, from May 2010 to May 2011. The time series for five HFCs and three PFCs showed occasionally high-concentration events while background conditions occurred for 36 % (HFC-32) to 83 % (PFC-218) of all measurements. The mean mixing ratios during background conditions were 24.5 ppt (parts per trillion, 10 −12 , molar) for HFC-23, 5.86 ppt for HFC-32, 9.97 ppt for HFC-125, 66.0 ppt for HFC-134a, 9.77 ppt for HFC-152a, 79.1 ppt for CF 4 , 4.22 ppt for PFC-116, and 0.56 ppt for PFC-218. The background mixing ratios for the compounds at SDZ are consistent with those obtained at mid to high latitude sites in the Northern Hemisphere. North-easterly winds were associated with negative contributions to atmospheric HFC and PFC loadings (mixing ratio anomalies weighted by time associated with winds in a given sector), whereas southwesterly advection (urban sector) showed positive loadings. Chinese emissions estimated by a tracer ratio method using carbon monoxide as tracer were 3.6 ± 3.2 kt yr −1 for HFC-23, 4.3 ± 3.6 kt yr −1 for HFC-32, 2.7 ± 2.3 kt yr −1 for HFC-125, 6.0 ± 5.6 kt yr −1 for HFC-134a, 2.0 ± 1.8 kt yr −1 for HFC-152a, 2.4 ± 2.1 kt yr −1 for CF 4 , 0.27 ± 0.26 kt yr −1 for PFC-116, and 0.061 ± 0.095 kt yr −1 for PFC-218. The lower HFC-23 emissions compared to earlier studies may be a result of the HFC-23 abatement measures taken as part of Clean Development Mechanism (CDM) projects that started in 2005.

We report ground-based atmospheric measurements and emission estimates for the halons

Abstract. High frequency, in situ observations from 11 globally distributed sites for the period 1994-2014 and archived air measurements dating from 1978 onward have been used to determine the global growth rate of 1,1-difluoroethane (HFC-152a, CH 3 CHF 2 ). These observations have been combined with a range of atmospheric transport models to derive global emission estimates in a topdown approach.

Abstract.A new method for measuring air temperature profiles in the atmospheric boundary layer at high spatial and temporal resolution is presented. The measurements are based on Raman scattering distributed temperature sensing (DTS) with a fiber optic cable attached to a tethered balloon. These data were used to estimate the height of the stable nocturnal boundary layer. The experiment was successfully deployed during a two-day campaign in September 2009, providing evidence that DTS is well suited for this atmospheric application. Observed stable temperature profiles exhibit an exponential shape confirming similarity concepts of the temperature inversion close to the surface. The atmospheric mixing height (MH) was estimated to vary between 5 m and 50 m as a result of the nocturnal boundary layer evolution. This value is in good agreement with the MH derived from concurrent Radon-222 ( 222 Rn) measurements and in previous studies.