Oxygen three-isotope analysis by secondary ion mass spectrometry of chondrule olivine and pyroxene in combination with electron microprobe analysis were carried out to investigate 24 FeO-poor (type I) and 2 FeO-rich (type II) chondrules from the Kaba (CV) chondrite. The Mg#'s of olivine and pyroxene in individual chondrules are uniform, which confirms that Kaba is one of the least thermally metamorphosed CV3 chondrites. The majority of chondrules in Kaba contain olivine and pyroxene that show indistinguishable Δ 17 O values (= δ 17 O − 0.52 × δ 18 O) within analytical uncertainties, as revealed by multiple spot analyses of individual chondrules. One third of chondrules contain olivine relict grains that are either 16 O-rich or 16 O-poor relative to other indistinguishable olivine and/or pyroxene analyses in the same chondrules. Excluding those isotopically recognized relicts, the mean oxygen isotope ratios (δ 18 O, δ 17 O, and Δ 17 O) of individual chondrules are calculated, which are interpreted to represent those of the final chondrule melt. Most of these isotope ratios plot on or slightly below the primitive chondrule mineral (PCM) line on the oxygen three-isotope diagram, except for the pyroxene-rich type II chondrule that plots above the PCM and on the terrestrial fractionation line. The Δ 17 O values of type I chondrules range from ~ −8‰ to ~ −4‰; the pyroxene-rich type II chondrule yields ~0‰, the olivine-rich type II chondrule ~ −2‰. In contrast to the ungrouped carbonaceous chondrite Acfer 094, the Yamato 81020 CO3, and the Allende CV3 chondrite, type I chondrules in Kaba only possess Δ 17 O values below −3‰ and a pronounced bimodal distribution of Δ 17 O values, as evident for those other chondrites, was not observed for Kaba.
We performed in situ oxygen three‐isotope measurements of chondrule olivine, pyroxenes, and plagioclase from the newly described CVRed chondrite NWA 8613. Additionally, oxygen isotope ratios of plagioclase in chondrules from the Kaba CV3OxB chondrite were determined to enable comparisons of isotope ratios and degree of alteration of chondrules in both CV lithologies. NWA 8613 was affected by only mild thermal metamorphism. The majority of oxygen isotope ratios of olivine and pyroxenes plot along a slope‐1 line in the oxygen three‐isotope diagram, except for a type II and a remolten barred olivine chondrule. When isotopic relict olivine is excluded, olivine, and low‐ and high‐Ca pyroxenes are indistinguishable regarding Δ17O values. Conversely, plagioclase in chondrules from NWA 8613 and Kaba plot along mass‐dependent fractionation lines. Oxygen isotopic disequilibrium between phenocrysts and plagioclase was caused probably by exchange of plagioclase with 16O‐poor fluids on the CV parent body. Based on an existing oxygen isotope mass balance model, possible dust enrichment and ice enhancement factors were estimated. Type I chondrules from NWA 8613 possibly formed at moderately high dust enrichment factors (50× to 150× CI dust relative to solar abundances); estimates for water ice in the chondrule precursors range from 0.2× to 0.6× the nominal amount of ice in dust of CI composition. Findings agree with results from an earlier study on oxygen isotopes in chondrules of the Kaba CV chondrite, providing further evidence for a relatively dry and only moderately high dust‐enriched disk in the CV chondrule‐forming region.
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