Many studies of transport through soil assume that the laboratory columns used in the experiments are packed homogeneously. This research evaluated a variety of dry and wet packing techniques for their ability to produce uniform packings of clean sands without the use of specialized equipment. The best dry packing technique consisted of the deposition of 0.2‐cm layers followed by compaction with a metal pestle. For the sand used in this study, this technique resulted in a porosity of 0.325 ± 0.0020. The best wet packing technique consisted of the deposition of thin layers of saturated sand into water while vibrating the column. This technique resulted in a denser and more uniform packing, with the porosity equaling 0.315 ± 0.0018. No significant lateral particle‐size segregation was observed for either technique. Despite their success in producing homogeneous columns, the techniques proved time consuming, taking about 1 h per 5 cm of packed depth to pack a 15‐cm square column.
Two-phase flow models of subsurface transport often require the constitutive relationship of capillary pressure as a function of saturation as part of the data input. This part of the study correlates the solution chemistry findings from the previous paper with observed changes in the primary drainage capillary pressure−saturation relationship for a fine- to medium-grained quartz porous medium. The results showed that the solution chemistry was directly reflected in the capillary pressure−saturation relationship. The major factor determining the degree of reduction in capillary pressure was the concentration and speciation of octanoic acid dissolved in the aqueous phase, the same variables reported in part 1 as critical in determining the surface and interfacial tension. Because measurements of the contact angle showed that the system stayed strongly hydrophilic under all conditions, the capillary pressure relationships could be scaled adequately using the appropriate values of surface or interfacial tension only. Since organic acid speciation had opposite effects on capillary pressure in the air−water and o-xylene−water systems, the impact of pH on the movement of a contaminant front will depend on whether the contamination occurs in the vadose zone (air−aqueous phase system) or saturated zone (organic liquid−aqueous phase system).
To describe the flow of water in unsaturated soils, the constitutive relationships of capillary pressure and relative permeability are necessary. To measure these relationships using traditional methods may require different experimental apparatuses and can be time‐consuming, particularly for multiple drainage and imbibition relationships for systems containing surfactants at various concentrations. Thus a critical need exists for an apparatus that can make rapid measurements. This paper outlines the design of an automated apparatus that can produce both capillary pressure and relative permeability relationships simultaneously and rapidly. The rapidity of the measurements is based on the use of a thin soil sample, a highly conductive capillary barrier, and stripper tensiometers. The capillary pressure is changed externally, with the change within the sample monitored through the use of tensiometers. Saturation is determined by monitoring the cumulative effluent, with the accuracy of the mass balance enhanced through the active removal of air bubbles from beneath the capillary barrier. A comparison of capillary pressure relationships for a fine‐grained sandy porous medium produced with this apparatus with those produced with a Tempe cell shows that this apparatus yields comparable measurements in about 2% of the time. Thus the burden of making multiple transport property measurements can be reduced considerably through the use of this apparatus.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.