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The first normal stress difference (N1) behavior of polymer nanocomposites and liquid crystalline polymer (LCP) composites is a measure of elasticity and is affected by shear stress as a result of morphological alterations at the molecular and nanostructure levels. In this study, the steady shear rheological behaviors of polylactide (PLA) and nanographite platelet (NGP) bionanocomposites containing 1, 2, 3, and 5 wt% nanofiller were investigated. The shear rheological properties of glass fiber‐filled LCPs (filler aspect ratio > 100) were also examined. One of the objectives of this study was to obtain a correlation between N1, filler contents, and shear stress/rate of the measurements. The results suggest that N1 in PLA/NGP bionanocomposites is dependent on the level of filler loading as well as the shear rate beyond a critical value. For the LCP systems, N1 is positive for the unfilled and negative for the glass fiber‐filled LCPs, respectively. A novel rectangular hyperbola model was successfully developed and utilized to fit the N1 data of the neat PLA and PLA/NGP composites as well as the unfilled LCPs. The anomalous N1 behavior of PLA/NGP and LCP composites was also thoroughly discussed in this study. POLYM. ENG. SCI., 54:1300–1312, 2014. © 2013 Society of Plastics Engineers

The shear viscosity and normal stress difference of two filled and two unfilled thermotropic liquid crystal polymer (TLCPs) were studied. The rigid and rod like molecules of TLCPs orientate differently at different shear rates. Under low shear rate, the molecules tend to align in the direction of the flow but also tumble and waggingo nt heir own axis. The abnormal orientation of the molecules also depends upon temperature, fillers contents, aspect ratio and elastic nature of LCP molecules. These behaviors lead to unusual rheological properties of LCPs, such as negative first normal stress difference for filled LCPs at low shear rates. But with the increase of shear rate, the molecules are oriented in the direction of flow, which lead to isotropic flow at high shear rates. The complicated rheological properties and characteristic anisotropic properties of LCPs are modelled by recently developed Leonov's viscoselastic constitutive equations. Simulation has been carried out using Mathematica software and the characteristic anisotropic properties of LCPs have been identified. The experimentally measured viscosities at high shear rate have been compared with model predictions. Moreover, the normal stress differences using at high shear rates have been estimated using Leonov's model, which is experimentally not accessible.

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