In the 1990s, restrictions on incineration encouraged the forest industry in western Canada to develop new uses for their wood residuals by product. One such use was as a replacement for cereal straw bedding in southern Alberta's beef cattle (Bos taurus) feedlot industry. However, use of carbon (C)-rich bedding, such as wood chips, had implications for subsequent composting of the feedlot manure, a practice that was being increasingly adopted. In a 3-yr study, we compared composting of wood chip-bedded manure (WBM) and barley (Hordeum vulgare L.) straw-bedded manure (SBM). There were no significant differences in temperature regimes of SBM and WBM, indicating similar rates of successful composting. Of 17 physical and chemical parameters, five showed significant (P < 0.10) differences due to bedding at the outset of composting (Day 0), and 11 showed significant differences at final sampling (Day 124). During composting (10 sampling times), seven parameters showed significant bedding effects, 16 showed significant time effects, and four showed a Bedding x Time interaction. Significantly lower (P < 0.10) losses of nitrogen (N) occurred with WBM (19%) compared with SBM (34%), which has positive implications for air quality and use as a soil amendment. Other advantages of WBM compost included significantly higher total C (333 vs. 210 kg Mg(-1) for SBM) and inorganic N (1.3 vs. 1.0 kg Mg(-1) for SBM) and significantly lower total phosphorus (4.5 vs. 5.3 kg Mg(-1) for SBM). Our results showed that wood chip bedding should not be a problem for subsequent composting of the manure after pen cleaning. In combination with other benefits, our findings should encourage the adoption of wood chips over straw as a bedding choice for southern Alberta feedlots.

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Effect of ionic strength on the kinetics of ionic and micellar reactions in aqueous solutionThe effect of the addition of "inert" salts on ionic reaction rates is discussed. For reactions between ions of the same charge sign, the effect is caused almost exclusively by the concentration and character of salt ions of charge sign opposite to that of the reactants. The rate is not dependent upon the ionic strength of the solutions. In reactions between ions of opposite charge sign, both salt ions may affect the rate, but the effect of one type may be dominant. The effects are quantitatively interpretable in terms of an ion association constant and specific rate constants for the associated and non-associated reactants. The further introduction of activity coefficients is not necessary. The reactions upon which the Livingston Diagram is based have been explored from this viewpoint and found to be in quantitative accord. 2

Flazasulfuron was evaluated for crop safety and efficacy on hair fescue (Festuca filiformis Pourr.) in wild blueberry (Vaccinium angustifolium Ait.) fields. Treatments consisted of flazasulfuron applied at 38 and 50 g a.i. ha−1 in fall of the bearing year and spring and fall of the non-bearing year. Industry standard fall bearing year pronamide (2240 g a.i. ha−1) and spring non-bearing year terbacil (2000 g a.i. ha−1) and foramsulfuron (35 g a.i. ha−1) applications were included for comparison. Pronamide consistently reduced flowering hair fescue tuft density in the non-bearing and bearing years across sites. Terbacil reduced flowering tuft inflorescence height in the non-bearing year, but did not reduce total or flowering tuft density in either year. Foramsulfuron reduced flowering tuft density and flowering tuft inflorescence number and height in the non-bearing year, but hair fescue recovered in the bearing year. Fall bearing year flazasulfuron applications did not reduce total or flowering tuft density or flowering tuft inflorescence number and height. In contrast, spring non-bearing year flazasulfuron applications reduced flowering tuft density and flowering tuft inflorescence number and height, though hair fescue recovered in these treatments in the bearing year. Fall non-bearing year flazasulfuron applications reduced hair fescue total tuft density, flowering tuft density, and flowering tuft inflorescence number in the bearing year. No treatments caused significant injury to wild blueberry. Flazasulfuron may contribute to improved hair fescue management in wild blueberry, and this herbicide should be evaluated further to confirm crop tolerance and identify potential use patterns with currently registered herbicides.

Dissipation of veterinary antimicrobials is known to occur during aerated windrow composting of beef cattle manure. However, it is unclear if a similar dissipation occurs during stockpiling. Chlortetracycline, tylosin, and sulfamethazine are three of the most commonly used veterinary antimicrobials in beef cattle production in western Canada. Their dissipation in stockpiled manure was investigated over 140 d during winter in Alberta, Canada. Beef cattle housed in pens were administered 44 mg of chlortetracycline kg feed (dry weight), 44 mg of chlortetracycline + 44 mg sulfamethazine kg feed, 11 mg of tylosin kg feed, or feed without antimicrobials (control). Manure samples were extracted using pressurized liquid extraction, and the extracts were analyzed for chlortetracycline, sulfamethazine, and tylosin by LC-MS-MS. Dissipation of all three antimicrobials in the manure was explained by exponential decay kinetics. Times for 50% dissipation (DT) were 1.8 ± 0.1 d for chlortetracycline alone or 6.0 ± 0.8 d when mixed with sulfamethazine, 20.8 ± 3.8 d for sulfamethazine, and 4.7 ± 1.2 d for tylosin. After 77 d, <1% of initial chlortetracycline and <2% of sulfamethazine remained. Tylosin residues were more variable, decreasing to approximately 12% of initial levels after 28 d, with 20% present after 77 d and 13% after 140 d. Temperatures within stockpiles reached maximum values within 6 d of establishment and varied with location (bottom, 62.5°C; middle, 63.8°C; and top, 42.9°C). Antimicrobials in the manure did not inhibit microbial activity, as indicated by temperature and mass losses of carbon (C) and nitrogen (N). The C/N ratio in the manure decreased over the stockpiling period, indicating decomposition of manure to a more stable state. Dissipation of excreted residues with DT values 1.8 to 20.8 d showed that stockpiling can be as effective as windrow composting in mitigating the transfer of these three veterinary antimicrobials into the environment during land application of processed manure.