Time-dependent photoexcitation and optical spectroscopy of pi-conjugated molecules is described using a new method for the simulation of excited state molecular dynamics in extended molecular systems with sizes up to hundreds of atoms. Applications are made to poly(p-phenylene vinylene) oligomers. Our analysis shows self-trapping of excitations on about six repeat units in the course of photoexcitation relaxation, identifies specific slow (torsion) and fast (bond-stretch) nuclear motions strongly coupled to the electronic degrees of freedom, and predicts spectroscopic signatures of molecular conformations.
The coexistence of distinct metallic and insulating electronic phases within the same sample of a perovskite manganite, such as La(1-x-y)Pr(y)Ca(x)MnO3, presents researchers with a tool for tuning the electronic properties in materials. In particular, colossal magnetoresistance in these materials--the dramatic reduction of resistivity in a magnetic field--is closely related to the observed texture owing to nanometre- and micrometre-scale inhomogeneities. Despite accumulated data from various high-resolution probes, a theoretical understanding for the existence of such inhomogeneities has been lacking. Mechanisms invoked so far, usually based on electronic mechanisms and chemical disorder, have been inadequate to describe the multiscale, multiphase coexistence within a unified picture. Moreover, lattice distortions and long-range strains are known to be important in the manganites. Here we show that the texturing can be due to the intrinsic complexity of a system with strong coupling between the electronic and elastic degrees of freedom. This leads to local energetically favourable configurations and provides a natural mechanism for the self-organized inhomogeneities over both nanometre and micrometre scales. The framework provides a physical understanding of various experimental results and a basis for engineering nanoscale patterns of metallic and insulating phases.
We predict a dynamical classical superfluid-insulator transition in a Bose-Einstein condensate trapped in an optical and a magnetic potential. In the tight-binding limit, this system realizes an array of weakly coupled condensates driven by an external harmonic field. For small displacements of the parabolic trap about the equilibrium position, the condensates coherently oscillate in the array. For large displacements, the condensates remain localized on the side of the harmonic trap with a randomization of the relative phases. The superfluid-insulator transition is due to a discrete modulational instability, occurring when the condensate center of mass velocity is larger than a critical value.
We study a model for the dynamical stretching of DNA which uses the stretching of the hydrogen bonds in a basepair as its main variable. We present a statistical mechanical analysis of the denaturation and specific heat curves, obtained with the transfer integral method; discreteness effects are treated exactly by a numerical solution of the transfer integral operator. Second order self-consistent phonon theory agrees with the exact transfer integral results in the low and intermediate temperature range and explains the phonon softening observed in the molecular dynamics simulations. When the temperature approaches the denaturation temperature, the second order self-consistent phonon results deviate significantly from the exact ones, pointing to the fundamental role of nonlinear processes in DNA denaturation.
In this paper we review a number of recent developments in the study of the Discrete Nonlinear Schrödinger (DNLS) equation. Results concerning ground and excited states, their construction, stability and bifurcations are presented in one and two spatial dimensions. Combinations of such steady states lead to the study of coherent structure bound states. A special case of such structures are the so-called twisted modes and their two-dimensional discrete vortex generalization. The ideas on such multi-coherent structures and their interactions are also useful in treating finite system effects through the image method. The statistical mechanics of the system is also analyzed and the partition function calculated in one spatial dimension using the transfer integral method. Finally, a number of open problems and future directions in the field are proposed.
Single-walled carbon nanotubes (SWNTs) are π-conjugated, quasi-one-dimensional structures consisting of rolled-up graphene sheets that, depending on their chirality, behave as semiconductors or metals 1 ; owing to their unique properties, they enable groundbreaking applications in mechanics, nanoelectronics and photonics 2,3 . In semiconducting SWNTs, medium-sized excitons (3-5 nm) with large binding energy and oscillator strength are the fundamental excitations 4-8 ; exciton wavefunction localization and one-dimensionality give rise to a strong electron-phonon coupling 9-11 , the study of which is crucial for the understanding of their electronic and optical properties. Here we report on the use of resonant sub-10-fs visible pulses 12 to generate and detect, in the time domain, coherent phonons in SWNT ensembles. We observe vibrational wavepackets for the radial breathing mode (RBM) and the G mode, and in particular their anharmonic coupling, resulting in a frequency modulation of the G mode by the RBM. Quantumchemical modelling 13 shows that this effect is due to a corrugation of the SWNT surface on photoexcitation, leading to a coupling between longitudinal and radial vibrations.Electron-phonon coupling in SWNTs is usually studied using Raman spectroscopy; this technique is useful for investigating ground-state vibrations 14 , whereas photoexcited-state vibrational dynamics remain largely unknown because, in the frequency domain, phonon replicas are hardly detectable in the presence of substantial inhomogeneous broadening. Time-domain observation of phonon dynamics has much lower sensitivity with respect to conventional Raman, but it enables direct measurement of excitedstate dynamics, vibrational dephasing and mode coupling in a distinct way 15,16 . Coherent phonon detection allows resolution in time of wavepacket dynamics that is otherwise averaged-out in standard Raman scattering.To detect coherent phonons in SWNTs, we use a standard pump-probe configuration, in which the observed quantity is the modulation depth in the differential transmission 17 ( T /T); details of the experimental setup are provided in the Methods section. Figure 1a shows T /T dynamics of SWNTs grown by the high-pressure carbon monoxide procedure dispersed in polymethylmethacrylate films following excitation with a sub-10-fs visible pulse (1.8-2.4 eV bandwidth), probed at an energy of 2.1 eV. The signal exhibits an initial photobleaching, which quickly turns into photoinduced absorption (PA). The fast photobleaching decay is ascribed to relaxation of the higher-lying exciton (second in an increasing energy scale) to the lower one, taking place with a 40-fs time constant 18 . The PA signal is generated by this lower exciton 4,5 and decays on the ps timescale, in agreement with previous results [19][20][21] . As shown in Fig. 1a, there is a clear oscillation in the T /T amplitude. The Fourier transform (FT) of the oscillatory component (Fig. 2a) shows a strong peak at 252 cm −1 (132-fs period). This frequency can be recognized as the RBM...
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