The article presents the results of the first known industrial trials for the processing of uranium-containing slag obtained during blast-furnace smelting of carbonaceous iron-uranium ore (Zhovtorichenske deposit, Ukraine). It is shown that the fractional precipitation of iron and aluminum impurities allows reducing the losses of uranium and increasing the degree of utilization of nitrate nitrogen and ammonia nitrogen, additionally producing the ammonium nitrate as fertilizer. The scheme for chemical concentrate processing ensured a significant increase in the degree of uranium deposition into the finished product – up to 60%. Nitric acid sludge processing technology made it possible to maintain the water balance and completely prevented the discharge of off-balance effluents into the river Dnipro.
This article presents the results of industrial tests of the technology of sorption, precipitation and extraction purification of the concentrate of rare earth elements (REE) from radioactive decay products of the uranium and thorium series. It has been shown that the combination of sorption, selective precipitation, and extraction processes makes it possible to effectively purify REE from U, Th, Po, Ra, RaD, and Ac and to obtain radiation-safe nitrogencontaining solutions for the production of fertilizers and individual REE.
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