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A wide range of the temperatures of hydrothermal fluid regime (430-103 °C) has been revealed in the result of microthermometric study of the fluid inclusions in the minerals of pre-ore and post-ore stages developed at the Elkon deposit. Average temperatures, as well as the temperature variation are similar for both pre-ore and post-ore stages. It allows sure determination of temperatures of uranium ore formation as 400-120 °C. Fluids possessed Na-chloride, rarely Na-chloride-carbonate composition and moderate salinity (6-16 wt. % · NaCl equiv.). The wide range of tem-peratures confirms an assumption made before that various temperatures were the reason of formation of uranium mineralization both in the form of predominantly amorphous phase (U-Ti-metagel), as well as the rarely crystalline form (brannerite). Abrupt temperature decrease was apparently the main factor of the ore precipitation.

It has been shown that the main uranium ore mineral, pitchblende (uranium dioxide), is a natural analog of synthetic uraninite (also uranium dioxide), which constitutes 96% of spent nuclear fuel (SNF). Geochronological studies of the U-Pb isotope systems in unaltered pitchblende from the orebodies reveal that these systems remained completely closed over the entire period (approximately 135 Ma) since the formation of the deposits. The bulk of the primary uranium ores within the Streltsovskoye ore field was influenced to various degrees by post-ore hydrothermal solutions that led to pitchblende spherulites being replaced by pseudomorphs of an amorphous phase with a U-Si composition; this phase also re-precipitated in veinlets proximal to the pitchblende pseudomorphs. A technique specially developed by the authors was used to carry out quantitative counts of the abundance of uranium minerals by calculating the uranium mass balance in one of the orebodies subjected to hydrothermal alteration. The calculations reveal minimal uranium loss from the orebody. Uranium liberated in the process of the pseudomorphic replacement of pitchblende was immediately fixed, in situ, in the newly formed coffinite-like amorphous U-Si phase as a result of the development of an efficient geochemical barrier that prevented the long-distance migration of uranium. In assessing the long-term safety of underground SNF repositories, the results of the present study give us confidence that SNF uraninite, in terms of the preservation of its integrity as a mineral phase, provides for the reliable long-term isolation of uranium, transuranium elements, and fission products that are "sealed" in the uraninite matrix. In the case of the mineral transformation of the uraninite matrix by hydrothermal solutions, the liberated uranium would be efficiently immobilized by the newly formed amorphous U-Si phase.

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