Molybdenum disulfide (MoS2) is systematically studied using Raman spectroscopy with ultraviolet and visible laser lines. It is shown that only the Raman frequencies of $ E_{2{\rm g}}^1 $ and $ A_{{\rm 1g}}^{} $ peaks vary monotonously with the layer number of ultrathin MoS2 flakes, while intensities or widths of the peaks vary arbitrarily. The coupling between electronic transitions and phonons are found to become weaker when the layer number of MoS2 decreases, attributed to the increased electronic transition energies or elongated intralayer atomic bonds in ultrathin MoS2. The asymmetric Raman peak at 454 cm−1, which has been regarded as the overtone of longitudinal optical M phonons in bulk MoS2, is actually a combinational band involving a longitudinal acoustic mode (LA(M)) and an optical mode ($ A_{{\rm 2u}}^{} $). Our findings suggest a clear evolution of the coupling between electronic transition and phonon when MoS2 is scaled down from three‐ to two‐dimensional geometry.

Ever since the first observation of all-optical switching of magnetization in the ferrimagnetic alloy GdFeCo using femtosecond laser pulses, there has been significant interest in exploiting this process for data-recording applications. in particular, the ultrafast speed of the magnetic reversal can enable the writing speeds associated with magnetic memory devices to be potentially pushed towards tHz frequencies. this work reports the development of perpendicular magnetic tunnel junctions incorporating a stack of tb/co nanolayers whose magnetization can be all-optically controlled via helicity-independent single-shot switching. toggling of the magnetization of the tb/co electrode was achieved using either 60 femtosecond-long or 5 picosecond-long laser pulses, with incident fluences down to 3.5 mJ/cm 2 , for co-rich compositions of the stack either in isolation or coupled to a cofeBelectrode/Mgo-barrier tunnel-junction stack. Successful switching of the cofeB-[tb/co] electrodes was obtained even after annealing at 250 °c. After integration of the [tb/co]-based electrodes within perpendicular magnetic tunnel junctions yielded a maximum tunneling magnetoresistance signal of 41% and RxA value of 150 Ωμm 2 with current-in-plane measurements and ratios between 28% and 38% in nanopatterned pillars. these results represent a breakthrough for the development of perpendicular magnetic tunnel junctions controllable using single laser pulses, and offer a technologically-viable path towards the realization of hybrid spintronic-photonic systems featuring tHz switching speeds. Ferrimagnetic systems based on rare earth (RE)-transition metal (TM) alloys and multilayers have been extensively studied in recent decades, largely due to their potential application in the field of magneto-optical recording 1. The strong perpendicular magnetocrystalline anisotropy inherent to amorphous RE-TM systems have allowed these alloys to play a key role in the historical transition from longitudinal to perpendicular magnetic recording structures 2 , and made them ideal for handling magnetic bit instabilities arising from superparamagnetic effects 3. Binary and ternary RE-TM systems such as GdFeCo, GdCo, TbCo or GdFe are still driving forward new developments pertaining to spintronic devices, including spin valves for magnetic read heads 4 , perpendicular magnetic tunnel junctions (p-MTJs) 5,6 or spin-orbit-torque phenomena 7. Recent works in this field have also revealed that RE-TM-based films (amorphous or multilayered) represent ideal materials for the observation and study of the phenomena of all-optical switching (AOS) 8-10. In these systems, it is possible to switch the magnetization using suitable laser pulses without the application of any external magnetic field. Depending on whether the laser-pulses need to be circularly-polarized, AOS of magnetization can be classed as either helicity-dependent (HD-AOS) or helicity-independent (HI-AOS). Furthermore, subject to the material in question, the switching process can be achieved with either a...