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This study was aimed at mapping the subsurface extent of saline water intrusions into aquifers at the eastern part of Dahomey basin, Nigeria. The study adopted geoelectric sounding methods. 108 vertical electrical soundings (VES) and 9 induced polarization soundings (IPS) data were acquired using Schlumberger array technique. Three aquifer units were delineated across the study area. The resistivity of the first, second and third aquifer layers varies from 0.2 to 1569 ohm-m, 0.5 to 904 ohm-m and 0.4 to 665 ohm-m respectively, while depth to the top of first, second and third aquifer varies respectively from 0.7 to 151.5 m, 1.4 to 305.5 m and 12.9 to 452.9 m. The depth to the first aquifer layer is shallow (less than 5 m) in the coastal area which makes this area to be highly vulnerable to anthropogenic pollution while their proximity to Atlantic Ocean makes them susceptible to saline water intrusion. In all the three aquifer units, the coastal area, Agbabu and other few locations in the mainland are characterized by low resistivity values (below 60 ohm-m) indicating possible presence of brackish or saline water. IP sounding results showed that all the low resistive layers in the mainland are characterized by clayey materials. The integration of VES and IPS results enabled the delineation of the saline water lateral extent across the study area. There is a strong direct correlation (r² = 0.8564) between location distance from the saline water source and depth to saline water in the study area. This can therefore serve as a predictive model to determine depth to saline water at any location within the saline water zone in the study area.

The study area occupies a part in southern Ilesa and is located within the schist belt of southwestern Nigeria, which embraces undifferentiated schist, gneisses, and migmatites with pegmatites, schist and epidorite complex, quartzite and quartz schist, granite gneiss, amphibolite, pegmatised schist, granulite, and gneiss. The study is aimed at clarifying the potential source of mineralization dealt with before in regional studies. Sixty-one soil samples were collected and analyzed for identifying these elements: Pb, Fe, Ni, Cd, Cr, Cu, Zn, and Mn. Multivariate analysis was done to obtain the coefficients of principal components from the standardized variables The elemental associations from the principal components analysis that accounted for 85.34% variability of the total variance are: Fe-Mn, Pb-Cr, and Cd-Zn. Comparably, these are equivalent with the previous results in the amphibolites and added the extension of association region to involve the schist and epidorite complex, quartzite, and quartz schist. The metallic association ratio revealed high metallic concentrations and led to the mineralization trend in southern Ilesa.

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A total of thirty-two (32) vertical electrical sounding (VES) data were acquired using R 50 d.c. Resistivity meter within the Precambrian basement geology of part of Akure metropolis southwestern Nigeria. The VES data were interpreted; eight type curves were identified, from the geoelectric section the subsurface was characterized into four lithologies namely topsoil, weathered layer (clay /lateritic clay), weathered / fractured basement and bedrock. Thus, two major aquifers were mapped these are weathered/partially weathered layer and weathered basement/fractured basement aquifers. These aquifers are characterized by thick overburden, found within basement depressions and exhibit moderate to relatively high values of coefficient of anisotropy, λ, (0.97-1.11) with depth. Also, ancient river channel trending approximately NE-SW was mapped. The assessment of the materials above the aquifers showed that longitudinal conductance (S), values ranged from 0.0035 to 0.17 mhos; thus the S values are generally low suggesting that the materials above the aquifers are loose and porous thus having less capacity to protect aquifers in the study area. Thus the aquifers are poorly protected, and by implication vulnerable to infiltration.