Earth-based radar observations and results from the MESSENGER mission have provided strong evidence that permanently shadowed regions near Mercury's poles host deposits of water ice. MESSENGER's complete orbital image and topographic datasets enable Mercury's surface to be observed and modeled under an extensive range of illumination conditions. The shadowed regions of Mercury's north polar region from 65°N to 90°N were mapped by analyzing Mercury Dual Imaging System (MDIS) images and by modeling illumination with Mercury Laser Altimeter (MLA) topographic data. The two independent methods produced strong agreement in identifying shadowed areas. All large radar-bright deposits, those hosted within impact craters ≥6 km in diameter, collocate with regions of shadow identified by both methods. However, only ∼46% of the persistently shadowed areas determined from images and ∼43% of the permanently shadowed areas derived from altimetry host radar-bright materials. Some sizable regions of shadow that do not host radar-bright deposits experience thermal conditions similar to those that do. The shadowed craters that lack radar-bright materials show a relation with longitude that is not related to the thermal environment, suggesting that the Earth-based radar observations of these locations may have been limited by viewing geometry, but it is also possible that water ice in these locations is insulated by anomalously thick lag deposits or that these shadowed regions do not host water ice.

Images acquired by NASA's MESSENGER spacecraft have revealed the morphology of frozen volatiles in Mercury's permanently shadowed polar craters and provide insight into the mode of emplacement and evolution of the polar deposits. The images show extensive, spatially continuous regions with distinctive reflectance properties. A site within Prokofiev crater identified as containing widespread surface water ice exhibits a cratered texture that resembles the neighboring sunlit surface except for its uniformly higher reflectance, indicating that the surficial ice was emplaced after formation of the underlying craters. In areas where water ice is inferred to be present but covered by a thin layer of dark, organic-rich volatile material, regions with uniformly lower reflectance extend to the edges of the shadowed areas and terminate with sharp boundaries. The sharp boundaries indicate that the volatile deposits at Mercury's poles are geologically young, relative to the time scale for lateral mixing by impacts, and either are restored at the surface through an ongoing process or were delivered to the planet recently.

Water ice has been delivered to the lunar poles from different sources over billions of years, but this accumulation was punctuated by large impacts that excavated dry regolith from depth and emplaced it in layers over the poles. Here, we model the resulting stratigraphies of ice and ejecta deposits in the lunar polar regions. Large polar craters were age dated, and their ejecta distributions calculated with standard scaling relations. We then created a Monte Carlo model for ice deposition and ejecta emplacement. Typical model runs showed that deposits in older cold traps (>4 Ga) are divided into two zones: buried ice-rich gigaton deposits and younger more gardened mantles. The latter are consistent with small crater morphometry measurements, but the existence of substantial ice buried at great depths is more difficult to confirm. Rare outlier model runs included Mercury-like cases with significant deposition events in recent history (<200 Ma). Plain Language Summary The polar regions of Earth's Moon have topographic depressions that are never directly exposed to the Sun, so they are cold enough for deposits of ice to exist. Water can get into these regions by water-bearing asteroids colliding with the Moon, or from lunar volcanoes erupting gases that travel to the poles. At the same time, large impact craters that form at the poles eject an enormous amount of soil and rock that could bury existing ice. It is not well understood how these two processes work together to build up deposits that may have alternating layers of ice-rich and ice-poor soil. In this study, we used computer simulations to predict what these layered deposits may look like. We found it is likely that large amounts of relatively pure ice are buried at depth in the oldest deposits, covered with thinner layers hosting less ice. Impact cratering has been the dominant process affecting the lunar poles, but the effects of large polar craters on nearby ice deposits have not been previously addressed. Impact effects have been considered for micrometeoroids (e.g.,

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Images obtained during the low‐altitude campaign in the final year of the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) mission provide the highest‐spatial‐resolution views of Mercury's polar deposits. Images for distinct areas of permanent shadow within 35 north polar craters were successfully captured during the campaign. All of these regions of permanent shadow were found to have low‐reflectance surfaces with well‐defined boundaries. Additionally, brightness variations across the deposits correlate with variations in the biannual maximum surface temperature across the permanently shadowed regions, supporting the conclusion that multiple volatile organic compounds are contained in Mercury's polar deposits, in addition to water ice. A recent large impact event or ongoing bombardment by micrometeoroids could deliver water as well as many volatile organic compounds to Mercury. Either scenario is consistent with the distinctive reflectance properties and well‐defined boundaries of Mercury's polar deposits and the presence of volatiles in all available cold traps.

anomalies are analyzed on the Moon's nearside. 20 • The amplitudes of the anomalies require a deep density contrast. • One 190-km anomaly with crater-related topography is suggestive of mantle uplift. • Marius Hills anomalies are consistent with intruded dike swarms. • An anomaly south of Aristarchus has a crater rim and possibly magmatic intrusions.

A transient lunar atmosphere formed during a peak period of volcanic outgassing and lasting up to about~70 Ma was recently proposed. We utilize forward-modeling of individual lunar basaltic eruptions and the observed geologic record to predict eruption frequency, magma volumes, and rates of volcanic volatile release. Typical lunar mare basalt eruptions have volumes of~10 2-10 3 km 3 , last less than a year, and have a rapidly decreasing volatile release rate. The total volume of lunar mare basalts erupted is small, and the repose period between individual eruptions is predicted to range from 20,000 to 60,000 years. Only under very exceptional circumstances could sufficient volatiles be released in a single eruption to create a transient atmosphere with a pressure as large as~0.5 Pa. The frequency of eruptions was likely too low to sustain any such atmosphere for more than a few thousand years. Transient, volcanically induced atmospheres were probably inefficient sources for volatile delivery to permanently shadowed lunar polar regions. Plain Language Summary Could gas emitted from volcanic eruptions during the most intense and voluminous period of lunar mare volcanism produce a temporary lunar atmosphere? Could the presence of such an atmosphere enable volatiles to reach the cold traps in the permanently shadowed regions at the lunar poles? We use information from lunar geology and sample analyses to predict the number of eruptions with time, the volume of individual eruptions, the rates of volcanic gas release during each eruption, and the time between eruptions. We find that only under rare circumstances could a single eruption or two eruptions closely spaced in time release enough gas to create a transient atmosphere with a pressure as large as~0.5 Pa. Furthermore, it is difficult to sustain such an atmosphere for more than a few thousand years. These results suggest that volcanically produced atmospheres are inefficient source mechanisms for delivery of volatiles to form deposits in permanently shadowed polar regions of the Moon; this favors volatile-rich impactors as the major source of polar ice.

The Mercury Laser Altimeter (MLA) measured surface reflectance, rs, at 1064 nm. On Mercury, most water‐ice deposits have anomalously low rs values indicative of an insulating layer beneath which ice is buried. Previous detections of surface water ice (without an insulating layer) were limited to seven possible craters. Here we map rs in three additional permanently shadowed craters that host radar‐bright deposits. Each crater has a mean rs value >0.3, suggesting that water ice is exposed at the surface without an overlying insulating layer. We also identify small‐scale cold traps (<5 km in diameter) where rs >0.3 and permanent shadows have biannual maximum surface temperatures <100 K. We suggest that a substantial amount of Mercury's water ice is not confined to large craters but exists within microcold traps, within rough patches and intercrater terrain.