Owing to the kinetic nature of the glass transition, the ability to significantly alter the properties of amorphous solids by the typical routes to the vitreous state is restricted. For instance, an order of magnitude change in the cooling rate merely modifies the value of the glass transition temperature (T(g)) by a few degrees. Here we show that matrix-assisted pulsed laser evaporation (MAPLE) can be used to form ultrastable and nanostructured glassy polymer films which, relative to the standard poly(methyl methacrylate) glass formed on cooling at standard rates, are 40% less dense, have a 40 K higher T(g), and exhibit a two orders of magnitude enhancement in kinetic stability at high temperatures. The unique set of properties of MAPLE-deposited glasses may make them attractive in technologies where weight and stability are central design issues.

The enhancement of stimulated Raman backscattering (SRBS) amplification was demonstrated by introducing a plasma density gradient along the pump and the seed interaction path and by a novel double-pass design. The energy transfer efficiency was significantly improved to a level of 6.4%. The seed pulse was amplified by a factor of more than 20 000 from the input in a 2mm long plasma, which also exceeded the intensity of the pump pulse by 2 orders of magnitude. This was accompanied by very effective pulse compression, from 500fsto90fs in the first pass measurements and in the second pass down to approximately 50fs, as it is indicated by the energy-pulse duration relation. Further improvements to the energy transfer efficiency and the SRBS performance by extending the region of resonance is also discussed where a uniform ∼4mm long plasma channel for SRBS was generated by using two subsequent laser pulses in an ethane gas jet.

A plasma-based resonant backward Raman amplifier/compressor for high power amplification of short laser pulses might, under ideal conditions, convert as much as 90% of the pump energy to the seed pulse. While the theoretical highest possible efficiency of this scheme has not yet been achieved, larger efficiencies than ever before obtained experimentally (6.4%) are now being reported, and these efficiencies are accompanied by strong pulse compression. Based on these recent extensive experiments, it is now possible to deduce that the experimentally realized efficiency of the amplifier is likely constrained by two factors, namely the pump chirp and the plasma wavebreaking, and that these experimental observations may likely involve favorable compensation between the chirp of the laser and the density variation of the mediating plasma. Several methods for further improvement of the amplifier efficiency in current experiments are suggested.

The development of a facile method for fabricating one-dimensional, precisely positioned nanostructures over large areas offers exciting opportunities in fundamental research and innovative applications. Large-scale nanofabrication methods have been restricted in accessibility due to their complexity and cost. Likewise, bottom-up synthesis of nanowires has been limited in methods to assemble these structures at precisely defined locations. Nanomaterials such as PbZr x Ti1−x O3 (PZT) nanowires (NWs)which may be useful for nonvolatile memory storage (FeRAM), nanoactuation, and nanoscale power generationare difficult to synthesize without suffering from polycrystallinity or poor stoichiometric control. Here, we report a novel fabrication method which requires only low-resolution photolithography and electrochemical etching to generate ultrasmooth NWs over wafer scales. These nanostructures are subsequently used as patterning templates to generate PZT nanowires with the highest reported piezoelectric performance (d eff ∼ 145 pm/V). The combined large-scale nanopatterning with hierarchical assembly of functional nanomaterials could yield breakthroughs in areas ranging from nanodevice arrays to nanodevice powering.

Coherent intense attosecond X-ray pulses could lead to a fast dynamical imaging of the biological macromolecules and other material nanostructures with a unique combination of a record high temporal and spatial resolution. Plasma based X-rays laser sources are capable to produce high energy X-ray pulses but with relatively long picosecond duration. The sources based on high-harmonic generation (HHG) of a laser field allow to produce much shorter pulses but of lower energy. We suggest two different paths towards intense sub-femtosecond X-ray sources, namely i) via efficient transformation of the picosecond radiation of the X-ray plasma lasers into the trains of sub-femtosecond pulses in a resonantly absorbing medium, and ii) via amplification of HHG radiation in the active medium of the X-ray plasma lasers. We show that essentially the same technique can be used for realization of both paths. This technique is a modulation of the parameters of the resonant transition (accordingly in absorbing or amplifying medium) produced under the action of sufficiently strong infrared or optical field. We propose experimental realization of the suggested technique in the passive/active media of i) Li III ions modulated by the mid-IR laser field and ii) C VI ions modulated by the optical laser radiation. I.