M. Feroci et al.Abstract High-time-resolution X-ray observations of compact objects provide direct access to strong-field gravity, to the equation of state of ultradense matter and to black hole masses and spins. A 10 m 2 -class instrument in combination with good spectral resolution is required to exploit the relevant diagnostics and answer two of the fundamental questions of the European Space Agency (ESA) Cosmic Vision Theme "Matter under extreme conditions", namely: does matter orbiting close to the event horizon follow the predictions of general relativity? What is the equation of state of matter in neutron stars? The Large Observatory For X-ray Timing (LOFT), selected by ESA as one of the four Cosmic Vision M3 candidate missions to undergo an assessment phase, will revolutionise the study of collapsed objects in our galaxy and of the brightest supermassive black holes in active galactic nuclei. Thanks to an innovative design and the development of large-area monolithic silicon drift detectors, the Large Area Detector (LAD) on board LOFT will achieve an effective area of ∼12 m 2 (more than an order of magnitude larger than any spaceborne predecessor) in the 2-30 keV range (up to 50 keV in expanded mode), yet still fits a conventional platform and small/medium-class launcher. With this large area and a spectral resolution of <260 eV, LOFT will yield unprecedented information on strongly curved spacetimes and matter under extreme conditions of pressure and magnetic field strength.

In this paper we present the enhanced X-ray Timing and Polarimetry mission. eXTP is a space science mission designed to study fundamental physics under extreme conditions of density, gravity and magnetism. The mission aims at determining the equation of state of matter at supra-nuclear density, measuring effects of QED, and understanding the dynamics of matter in strong-field gravity. In addition to investigating fundamental physics, eXTP will be a very powerful observatory for astrophysics that will provide observations of unprecedented quality on a variety of galactic and extragalactic objects. In particular, its wide field monitoring capabilities will be highly instrumental to detect the electro-magnetic counterparts of gravitational wave sources. The paper provides a detailed description of: 1) The technological and technical aspects, and the expected performance of the instruments of the scientific payload; 2) The elements and functions of the mission, from the spacecraft to the ground segment.X-ray instrumentation, X-ray Polarimetry, X-ray Timing, Space mission: eXTP PACS number(s): 95.55. Ka, 95.85.Nv, 95.75.Hi, 97.60.Jd, 97.60.Lf

A c c e p t e d m a n u s c r i p t remote sensing and will make measurements on spatial scales of less than 10 km for 57 major elements during solar flares, sufficient to isolate surface landforms, such as craters 58 and their internal structures. The spatial resolution achieved by MIXS-T is made possible 59 by novel, low mass microchannel plate X-ray optics, in a Wolter type I optical geometry. 60 61 MIXS measurements of surface elemental composition will help determine rock types, 62 the evolution of the surface and ultimately a probable formation process for the planet. In 63 this paper we present MIXS and its predicted performance at Mercury as well as 64 discussing the role that MIXS measurements will play in answering the major questions 65 about Mercury. 66 67

ABSTRACTeXTP is a science mission designed to study the state of matter under extreme conditions of density, gravity and magnetism. Primary goals are the determination of the equation of state of matter at supra-nuclear density, the measurement of QED effects in highly magnetized star, and the study of accretion in the strong-field regime of gravity. Primary targets include isolated and binary neutron stars, strong magnetic field systems like magnetars, and stellar-mass and supermassive black holes. The mission carries a unique and unprecedented suite of state-of-the-art scientific instruments enabling for the first time ever the simultaneous spectral-timing-polarimetry studies of cosmic sources in the energy range from 0.5-30 keV (and beyond). Key elements of the payload are: the Spectroscopic Focusing Array (SFA) -a set of 11 X-ray optics for a total effective area of ∼0.9 m 2 and 0.6 m 2 at 2 keV and 6 keV respectively, equipped with Silicon Drift Detectors offering <180 eV spectral resolution; the Large Area Detector (LAD) -a deployable set of 640 Silicon Drift Detectors, for a total effective area of ∼3.4 m 2 , between 6 and 10 keV, and spectral resolution better than 250 eV; the Polarimetry Focusing Array (PFA) -a set of 2 X-ray telescope, for a total effective area of 250 cm 2 at 2 keV, equipped with imaging gas pixel photoelectric polarimeters; the Wide Field Monitor (WFM) -a set of 3 coded mask wide field units, equipped with position-sensitive Silicon Drift Detectors, each covering a 90 degrees x 90 degrees field of view. The eXTP international consortium includes major institutions of the Chinese Academy of Sciences and Universities in China, as well as major institutions in several European countries and the United States. The predecessor of eXTP, the XTP mission concept, has been selected and funded as one of the so-called background missions in the Strategic Priority Space Science Program of the Chinese Academy of Sciences since 2011. The strong European participation has significantly enhanced the scientific capabilities of eXTP. The planned launch date of the mission is earlier than 2025.

The ESA-JAXA BepiColombo mission will provide simultaneous measurements from two spacecraft, offering an unprecedented opportunity to investigate magnetospheric The BepiColombo mission to Mercury Edited by Johannes Benkhoff, Go Murakami and Ayako Matsuoka B A. Milillo

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Real-time monitoring of the Suzuki–Miyaura reaction using mass spectrometry during sequential addition of the various reaction components suggests that a dynamic series of equilibria exist in these solutions. Depending on conditions, the boronic acid can be dehydrated, deprotonated, hydroxylated (or alkoxylated), or fluorinated. Palladium–phosphine species present include Pd(0) (to which the aryl iodide rapidly oxidatively adds), the Pd­(II) aryl iodide complex, a cationic Pd­(II) species formed by dissociation of the iodide ligand, and the Pd­(II) bisaryl complex that ultimately extrudes the product through reductive elimination. No fluorinated or hydr­(alk-)­oxylated palladium complexes were observed under catalytic conditions. Several transmetalation combinations were excluded as reactive partners, but several possibilities remain, and more than one mechanism is likely to be operative, even under similar conditions.

The LOFT mission concept is one of four candidates selected by ESA for the M3 launch opportunity as Medium Size missions of the Cosmic Vision programme. The launch window is currently planned for between 2022 and 2024. LOFT is designed to exploit the diagnostics of rapid X-ray flux and spectral variability that directly probe the motion of matter down to distances very close to black holes and neutron stars, as well as the physical state of ultradense matter. These primary science goals will be addressed by a payload composed of a Large Area Detector (LAD) and a Wide Field Monitor (WFM). The LAD is a collimated (<1 degree field of view) experiment operating in the energy range 2-50 keV, with a 10 m2 peak effective area and an energy resolution of 260 eV at 6 keV. The WFM will operate in the same energy range as the LAD, enabling simultaneous monitoring of a few-steradian wide field of view, with an angular resolution of <5 arcmin. The LAD and WFM experiments will allow us to investigate variability from submillisecond QPO's to yearlong transient outbursts. In this paper we report the current status of the project