After exfoliation of graphite and discovered graphene in 2004 by Novoselov and Geim, the attention of graphene by the global scientific community enhanced progressively as a multifunctional wonder material in the world due to its unique extraordinary properties.Numerous methods apart from the discovered method have been investigated to synthesize the graphene in mass scale for variety of applications. Consequently, we believe that an adequate knowledge is necessary to choose a proper method of synthesis for a particular application. The main objective of the present review is to summarize the feasible methods followed in synthesis of graphene, discussing their properties, applications, advantages, and disadvantages for future prospects.