Depolarized dynamic light scattering (DDLS) experiments are reported on three different systems: on
tobacco mosaic virus as a well investigated sample; on PEO−PPO−PEO triblock copolymer micelles, which
show sphere-to-rod transition with increasing temperature; and on a microemulsion of the type water/octane/C
i
E
j
. DDLS measurements were performed using highly discriminating polarizers and single-mode
fiber detection at different scattering angles, obtaining decay rates Γ
VH versus scattering angle. The rotational
and translational diffusion coefficients available from these plots were taken to evaluate size parameters
of the systems using Broersma's expressions for a stiff rod. Good agreement with theory and literature
was found in the case of tobacco mosaic virus and at concentrations below the overlap concentration c*
for the other two systems.
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