The effect of the structure of radical catalysts, N hydroxyphthalimides (NHPI), on the oxida tion process initiation in the presence of cobalt (II) acetate is studied. It is shown that the magnitude of the synergic effect of the system NHPI-Co(OAc) 2 depends on the structure of NHPI molecule. The proposed mechanism is confirmed according to which of the NHPI molecules in the inner sphere of the metal are catalytically active.
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