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Construction materials that incorporate into their structures photocatalysts are found to exhibit a capacity in removing NO from air. Therefore, the development of such innovative materials with both de-soiling and de-polluting properties is a significant step towards the improvement of indoor and outdoor air quality.It is the purpose of this study to investigate the photocatalytic removal of dominant urban air pollutant (NO) using TiO 2 -modified ceramic tiles under both static and dynamic conditions. The activity of 4 types of these materials was investigated in an environmental chamber (0.125m 3 ) under a realistic level of irradiation, humidity and compound amount with reference to a typical urban air pollutant concentration. The photocatalytic performance of the materials was evaluated through the calculation of two parameters: the a) photocatalytic decomposition percentage (PD %) and the b) photocatalytic rate (PR μg m -2 s -1 ) Results showed that building materials, such as ceramic tiles, when treated with different layers of 10% TiO 2 , can be used for the photocatalytic removal of air pollutants under "real" world conditions. A NO degradation percentage high as 75%, and a decomposition rate the size of 0.65 μg m -2 s -1 were reported for the 4-layer TiO 2 material under static mode, whereas the corresponding parameters were found to be 50% and 0.63 μgm -2 s -1 respectively in the dynamic system. Overall, it was exhibited that the PR parameter presented the same trend and level under both operational modes for all materials, whereas the %PD parameter displayed higher values when studied under static mode.

Transparent counter electrodes were prepared on transparent conductive glass (TCG) substrates from a hexachloroplatinic acid (H2PtCl6) solution applying the thermal decomposition method in combination with the spin-coating deposition technique. The effect of the precursor concentration and the number of deposited platinum layers on the surface characteristics of the Pt films was examined, and the relation between those surface characteristics and the electrochemical properties of the corresponding modified Pt/TCG electrodes was defined. Four types of counterelectrodes were prepared, differing in the concentration of the H2PtCl6 solution (0.03M and 0.15M) and in the number of Pt layers (one or two Pt layers); their performance as counterelectrodes was evaluated after their incorporation into dye-sensitized solar cells (DSSCs) employing a solid state redox electrolyte. The obtained results show that solar cells using counterelectrodes prepared from the 0.03MH2PtCl6 solution and consisting of two Pt layers (Pt032 electrode) exhibited the best performance characteristics (diffusion coefficient D*I3−=1.58×10−5cm2s−1, conversion efficiency η=2.16%, fill factor ff=62.14%, and short circuit photocurrent Isc=4.71mAcm−2). The electrochemical behavior of the modified counterelectrodes is consistent with the surface characteristics of the Pt film that formed on the conductive glass substrate, which seems to be significantly affected by the adopted method and the adjusted experimental parameters (Pt concentration and number of Pt layers). Specifically, this type of electrodes beside their low roughness (Rq=11.5nm), also presents a high complexity (Df=2.3). As a result, for this kind of solid state DSSCs, the less rough but the more complex the Pt/TCG electrode surface, the higher the efficiency of the corresponding solar cells.