Background: Radionuclides occur in coal combustion residues, such as fly ash and bottom ash, which are by-products of coal combustion. They pose potential radiological risks to people present in the surrounding areas. Materials and Methods: Gamma spectrometry was performed to determine the radionuclide activity concentrations in a coal-driven power plant located in the Limpopo province, South Africa, to assess the radiological impacts of the ash stored in ash dumps adjacent to the plant. Results: The mean (+ SD) activity concentrations were found to be 144.3±4, 62±2.1, and 315.9±4.9 Bq/ kg for 226 Ra, 232 Th, and 40 K, respectively, which are comparable to those found in previous studies. The radium equivalent activity was determined to be 258.43 Bq/kg. The average values of internal and external hazard indices were 1.09 and 0.70, respectively. With the exception of the internal hazard index, all the other indices were within the prescribed ranges indicated by the literature. Furthermore, the mean total annual effective dose received by plant workers was found to be 0.070 mSv/y, which is within the limit of 1.0 mSv/y prescribed by the IAEA. The average excess lifetime cancer risk value was 0.49 × 10 -3 , which is higher than the UNSCEAR precautionary limit of 0.29 × 10 -3 but lower than the ICRP limit of 0.05 for low-level radiation. Conclusion: Ash dust inhalation was identified as the most significant exposure pathway among plant workers. However, the results demonstrated that storing of ash at this plant does not constitute any radiological threat to people in the adjacent regions.
Coal-fired power plants (CFPP) provide approximately 40% of the world's energy demand. Naturally occurring radioactive materials (NORM) contained in coal become enriched in coal combustion residues as a result of the elimination of carbon during combustion. The fly ash and bottom ash produced from CFPP may be significant sources of exposure to naturally occurring radionuclides for the population near the combustion plant or ash dumps. Despite this fact, very few studies have actually addressed the relationship of the NORM enrichment factors and the quality of coal used. This paper aims to relate the quality of coal to the enrichment factors for the radionuclides of interest (K 40 , Ra 226 , Th 232 and Po 210) in coal combustion residues from three South African CFPP. The data from other CFPP was also taken into account to establish this correlation. The feedstock coal used in these CFPP is typically low quality, with ash content in the range of 25-45 wt%. The radionuclides investigated were determined by gamma spectrometry with the exception of Po 210 , which was determined by alpha spectrometry. The enrichment factors for the radionuclides of K 40 , Ra 226 , Th 232 and Po 210 in the fly ash and bottom ash (except Po 210) was found to be directly proportional to the quality of coal. That is when the ash percentage increased (coal quality decreased) the enrichment factor decreased. The Po 210 radionuclide in the bottom ash had an enrichment factor less than one. The relationship between coal quality and enrichment factors for the radionuclides of K 40 , Ra 226 , Th 232 and Po 210 in both the fly ash and bottom ash (except Po 210 in the bottom ash) was demonstrated by the following mathematical equation: () 1 Enrichment Factor Ash % in feed coal =. This equation may be used as a good indication in obtaining an estimate in determining the enrichment of How to cite this paper: Ahmed, U.A.Q. and Joubert, A. (2019) Establishing a Relationship between Coal Quality and the Enrichment of Radionuclides in Coal Combustion Residues.
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