ABSTRACT:Coatings prepared from polyesteramide resin synthesized from linseed oil, a renewable resource, have been found to show improved physicomechanical and anticorrosive characteristics. These properties are further improved when aluminum is incorporated in the polyesteramide resin. The coatings of this resin are generally obtained by baking at elevated temperatures. With a view toward the use of linseed oil, as a precursor for the synthesis of polyesteramide resins and to cure their coatings at ambient temperature, toluylene diisocyanate (TDI) was incorporated into polyesteramide and alumina-filled polyesteramide in varying proportions to obtain urethane-modified resins. The latter resins were found to cure at room temperature. The broad structural features of the urethane-modified polyesteramide and alumina-filled polyesteramide were confirmed by FTIR and 1 H-NMR spectroscopies. Scratch hardness; impact resistance; bending resistance; specular gloss; and resistance to acid, alkali, and organic solvents of the coatings of these resins were determined by standard methods. Physicomechanical and anticorrosive properties, specular gloss, and thermal stability of the urethane-modified alumina-filled polyesteramide coatings were found to be at higher levels among these resins. It was found that TDI could be incorporated in polyesteramide up to only 6 wt %, such that above this loading its properties started to deteriorate, whereas alumina-filled polyesteramide could take up to 10 wt % TDI. Explanation is provided for the increase in scratch hardness and impact resistance above 6 and 10 wt % addition of TDI in polyesteramide and alumina-filled polyesteramide, respectively, as well as for the decrease in flexibility and resistance to solvents, acid, and alkali of coatings of these resins above these limits of TDI addition.

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