The solar chemical composition is an important ingredient in our understanding of the formation, structure and evolution of both the Sun and our solar system. Furthermore, it is an essential reference standard against which the elemental contents of other astronomical objects are compared. In this review we evaluate the current understanding of the solar photospheric composition. In particular, we present a redetermination of the abundances of nearly all available elements, using a realistic new 3-dimensional (3D), time-dependent hydrodynamical model of the solar atmosphere. We have carefully considered the atomic input data and selection of spectral lines, and accounted for departures from LTE whenever possible. The end result is a comprehensive and homogeneous compilation of the solar elemental abundances. Particularly noteworthy findings are significantly lower abundances of carbon, nitrogen, oxygen and neon compared with the widely-used values of a decade ago. The new solar chemical composition is supported by a high degree of internal consistency between available abundance indicators, and by agreement with values obtained in the solar neighborhood and from the most pristine meteorites. There is, however, a stark conflict with standard models of the solar interior according to helioseismology, a discrepancy that has yet to find a satisfactory resolution.

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Abstract. The solar photospheric oxygen abundance has been determined from [O ], O , OH vibration-rotation and OH pure rotation lines by means of a realistic time-dependent, 3D, hydrodynamical model of the solar atmosphere. In the case of the O  lines, 3D non-LTE calculations have been performed, revealing significant departures from LTE as a result of photon losses in the lines. We derive a solar oxygen abundance of log O = 8.66 ± 0.05. All oxygen diagnostics yield highly consistent abundances, in sharp contrast with the results of classical 1D model atmospheres. This low value is in good agreement with measurements of the local interstellar medium and nearby B stars. This low abundance is also supported by the excellent correspondence between lines of very different line formation sensitivities, and between the observed and predicted line shapes and center-to-limb variations. Together with the corresponding down-ward revisions of the solar carbon, nitrogen and neon abundances, the resulting significant decrease in solar metal mass fraction to Z = 0.0126 can, however, potentially spoil the impressive agreement between predicted and observed sound speed in the solar interior determined from helioseismology.

We present our current knowledge of the solar chemical composition based on the recent significant downward revision of the solar photospheric abundances of the most abundant metals. These new solar abundances result from the use of a 3D hydrodynamic model of the solar atmosphere instead of the classical 1D hydrostatic models, accounting for departures from LTE, and improved atomic and molecular data. With these abundances, the new solar metallicity, Z, decreases to Z = 0.012, almost a factor of two lower than earlier widely used values. We compare our values with data from other sources and analyse a number of impacts of these new photospheric abundances. While resolving a number of longstanding problems, the new 3D-based solar photospheric composition also poses serious challenges for the standard solar model as judged by helioseismology.

Abstract. The solar photospheric carbon abundance has been determined from [C ], C , CH vibration-rotation, CH A-X electronic and C 2 Swan electronic lines by means of a time-dependent, 3D, hydrodynamical model of the solar atmosphere.Departures from LTE have been considered for the C  lines. These turned out to be of increasing importance for stronger lines and are crucial to remove a trend in LTE abundances with the strengths of the lines. Very gratifying agreement is found among all the atomic and molecular abundance diagnostics in spite of their widely different line formation sensitivities. The mean value of the solar carbon abundance based on the four primary abundance indicators ([C ], C , CH vibration-rotation, C 2 Swan) is log C = 8.39 ± 0.05, including our best estimate of possible systematic errors. Consistent results also come from the CH electronic lines, which we have relegated to a supporting role due to their sensitivity to the line broadening. The new 3D based solar C abundance is significantly lower than previously estimated in studies using 1D model atmospheres.