Beijing has experienced a rapid urbanization in the last few decades and has been suffering from serious air pollution during recent years. The Weather Research and Forecasting‐Chem model is used to quantify the effects of urbanization on regional climate and air quality and those of urban heat island (UHI) mitigation strategy on urban air quality in Beijing, with a special focus on the impacts under different weather conditions (heat waves in summer and polluted days in winter). The modification of rural land use into urban impervious surface significantly increases 2‐m temperature (T2) and planetary boundary layer height but decreases 2‐m relative humidity (RH2) and 10‐m wind speed (WS10) in urban Beijing, which further leads to the increases in surface‐layer O3 concentrations of 9.5 ppbv in summer and 1.8 ppbv in winter and the decreases in PM2.5 concentrations of 16.6 μg m−3 in summer and 26.2 μg m−3 in winter. Compared with normal days (clean days), the UHI intensity is enhanced by 11.1% during heat waves in summer (by 16.7% during polluted days in winter). Although increasing urban albedo is an effective mitigation strategy to decrease UHI intensity, it worsens the urban air quality. When the urban albedo increases from 0.2 to 0.85, the daily average PM2.5 concentrations are increased by 10.2 (6.1) μg m−3 in summer (in winter), and the daily maximum O3 concentrations are increased by 12.8 ppbv under heat waves in summer.

Volatile organic compounds (VOCs), ozone (O3), nitrogen oxides (NOx), carbon monoxide (CO), meteorological parameters, and total non-methane hydrocarbons (NMHC) were analyzed from simultaneous measurements at the MSU-IAP (Moscow State University—Institute of Atmospheric Physics) observational site in Moscow from 2011–2013. Seasonal and diurnal variability of the compounds was studied. The highest O3 concentration in Moscow was observed in the summer daytime periods in anticyclonic meteorological conditions under poor ventilation of the atmospheric boundary layer and high temperatures (up to 105 ppbv or 210 μg/m3). In contrast, NOx, CO, and benzene decreased from 8 a.m. to 5–6 p.m. local time (LT). The high positive correlation of daytime O3 with secondary VOCs affirmed an important role of photochemical O3 production in Moscow during the summers of 2011–2013. The summertime average concentrations of the biogenic VOCs isoprene and monoterpenes were observed to be 0.73 ppbv and 0.53 ppbv, respectively. The principal source of anthropogenic VOCs in Moscow was established to be local vehicle emissions. Yet, only about 5% of the observed isoprene was safely attributed to anthropogenic sources, suggesting significant contribution of biogenic sources into the total levels of ozone precursors. The non-linear O3–NOx dependence shows a decrease in ground-level O3 with an increase in NOx during the summers of 2011–2013, which is typical for the VOC-sensitive photochemical regime of O3 formation. Nevertheless, during the elevated ozone episodes in July 2011, the photochemical regime of ozone production was either transitional or NOx-sensitive. Contribution of various anthropogenic and biogenic VOCs into the measured ozone values was evaluated. The ozone-forming potential (OFP) of total VOCs was 31–67 μg/m3 on average and exceeded 100 μg/m3 in the top 10% of high ozone events, reaching 136 μg/m3. Acetaldehyde, 1.3-butadiene, and isoprene have the highest ozone production potential in Moscow compared to that of other measured VOCs.

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