Die Darstellung von Diphosphortetrabromid, das vermutlich aufgrund seiner starken Dissoziationsneigung bisher nicht erhalten wurde, gelingt erstmalig als Cr‐Komplex (II) durch Substitutionsreaktion an der Diphosphin‐Brücke des diphosphinverbrückten Crcarbonyl‐Komplexes (I).
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