Octan-Z-ol and silicon tetrachloride formed chlorosilanes and tetra-2octyloxysilane in proportions depending on the proportion of silicon tetrachloride, but none of the chloride, RCl. (+)-1-Phenylethanol formed considerably racemised chloride, RCl, under similar conditions. Whereas hydrogen chloride had no action on tetra-2-octyloxysilane, it rapidly dealkylated the corresponding (+ ) -1-phenylethyl compound, the chloride formed being considerably racemised. In the presence of py-ridine a number of tetraalkyloxysilanes have been obtained in excellent yield. These and other data are now available for comparison with those from a study of phosphorus trichloride-alcohol systems, and provide a contribution to the eventual elucidation of mechanism.
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