The most common description of the mechanical behaviour of viscoelastic materials is presented using complex dynamic properties. These properties depend on many external factors (temperature, excitation frequency, etc.) and determine the evolution of derivative effects in the structure. The purpose of the conducted investigations is the determination of the influence of heating rate on the dynamic mechanical behaviour of a polymer based composite material under different excitation frequencies and temperatures. The glass transition temperatures and the activation energies of the phase transition were calculated, which allow extending the Arrhenius equation by the heating rate factor. The obtained dependencies could be useful for the estimation of the mechanical and thermal degradations of polymeric composites and, among others, for the determination of the self-heating temperature distributions and their evolution during cyclic loading. The presented results could also be applied for the determination of fatigue, crack growth and residual life of composite structures.
This paper presents an analysis of the impact of modification of thermomechanical properties of polymer materials on the process of gear wheel machining on a CNC machine tool. Polymer materials Tecaflon (PVDA) and polyethylene (PE) were used for processing. The materials underwent thermal modification i.e., annealing. Prepared samples (gear wheel dimensions Ø76.5 × 20 mm) were machined under the same conditions, only changing the feed rate parameter. A CNC milling machine of its own construction was used for machining with a horizontal numerical dividing attachment. The obtained gear wheels were tested using ZEISS GEAR PRO gear analyzes software. Deviations of the involute outline and the tooth line allowed classification of wheels in the 9th grade of accuracy. Machined teeth surfaces were examined for changes in the properties of surface layer, taking into account the influence of polymer material thermal modification on the surface condition. The samples were tested for mechanical properties (tensile strength) and thermomechanical properties (DSC and DMTA). The tests showed positive changes in material strength and significant improvements in PVDA Tecaflon after heat treatment.
The paper is about a new class of antimicrobial functional nanomaterials. Proposed compounds are based on SBA-15 porous silica matrices and contain anchored copper ions. Thanks to the immobilization of functional groups the compounds are safer for environment than commonly used disinfectant agents. We prepared and examined silica based materials containing two concentrations of copper-containing groups: 10 and 5%. For the reference we prepared samples containing free-standing CuO molecules in the structure and checked their antimicrobial properties. Antibacterial effect of considered SBA-15-Cu material was tested onEscherichia colibacteria. Antimicrobial tests were applied for the pure form of the material and as modifying agents for plastics. The obtained results showed that the sample with lower concentration of active copper-containing groups has stronger antimicrobial properties than the one with higher concentration of copper. Interestingly, silica containing free-standing CuO molecules has no antimicrobial properties. Considering the obtained results, we can conclude that the most probable antimicrobial mechanism in this case is an oxidation stress. When a plastic modifier is applied the material is enriched with bacterial inhibitory properties. It seems that SBA-15 silica containing low concentration of anchored copper ions is promising in terms of its antibacterial property and biomaterial potential for commercial use.
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