Infrared radiation emitted from a planet contains information about the chemical composition and vertical temperature profile of its atmosphere. If upper layers are cooler than lower layers, molecular gases will produce absorption features in the planetary thermal spectrum. Conversely, if there is a stratosphere-where temperature increases with altitude-these molecular features will be observed in emission. It has been suggested that stratospheres could form in highly irradiated exoplanets, but the extent to which this occurs is unresolved both theoretically and observationally. A previous claim for the presence of a stratosphere remains open to question, owing to the challenges posed by the highly variable host star and the low spectral resolution of the measurements. Here we report a near-infrared thermal spectrum for the ultrahot gas giant WASP-121b, which has an equilibrium temperature of approximately 2,500 kelvin. Water is resolved in emission, providing a detection of an exoplanet stratosphere at 5σ confidence. These observations imply that a substantial fraction of incident stellar radiation is retained at high altitudes in the atmosphere, possibly by absorbing chemical species such as gaseous vanadium oxide and titanium oxide.

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We present HST near-ultraviolet (NUV) transits of the hot Jupiter WASP-121b, acquired as part of the PanCET program. Time series spectra during two transit events were used to measure the transmission spectra between 2280 and 3070Å at a resolution of 30,000. Using HST data from 61 STIS visits, we show that data from HST's Pointing Control System can be used to decorrelate the instrument systematic errors (Jitter Decorrelation), which we used to fit the WASP-121b light curves. The NUV spectrum show very strong absorption features, with the NUV white light curve found to be larger than the average optical and near-infrared value at 6-σ confidence. We identify and spectrally resolve absorption from the Mg ii doublet in the planetary exosphere at a 5.9-σ confidence level. The Mg ii doublet is observed to reach altitudes of R pl /R star = 0.284 ± 0.037 for the 2796Å line and 0.242 ± 0.0431 in the 2804Å line, which exceeds the Roche lobe size as viewed in transit geometry (R eqRL /R star = 0.158). We also detect and resolve strong features of the Fe ii UV1 and UV2 multiplets, and observe the lines reaching altitudes of R pl /R star ≈ 0.3. At these high altitudes, the atmospheric Mg ii and Fe ii gas is not gravitationally bound to the planet, and these ionized species may be hydrodynamically escaping or could be magnetically confined. Refractory Mg and Fe atoms at 2 Sing et al.high altitudes also indicates that these species are not trapped into condensate clouds at depth, which places constraints on the deep interior temperature.

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One of the most intriguing, long‐standing questions regarding Venus's atmosphere is the origin and distribution of the unknown UV absorber, responsible for the absorption band detected at the near‐UV and blue range of Venus's spectrum. In this work, we use data collected by Mercury Atmospheric and Surface Composition Spectrometer (MASCS) spectrograph on board the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) mission during its second Venus flyby in June 2007 to address this issue. Spectra range from 0.3 μm to 1.5 μm including some gaseous H2O and CO2 bands, as well as part of the SO2 absorption band and the core of the UV absorption. We used the NEMESIS radiative transfer code and retrieval suite to investigate the vertical distribution of particles in the equatorial atmosphere and to retrieve the imaginary refractive indices of the UV absorber, assumed to be well mixed with Venus's small mode 1 particles. The results show a homogeneous equatorial atmosphere, with cloud tops (height for unity optical depth) at 75 ± 2 km above surface. The UV absorption is found to be centered at 0.34 ± 0.03 μm with a full width at half maximum of 0.14 ± 0.01 μm. Our values are compared with previous candidates for the UV aerosol absorber, among which disulfur oxide (S2O) and dioxide disulfur (S2O2) provide the best agreement with our results.