A new identification and indexing for the phase BaAl2Ti5O14 were accomplished using an X‐ray diffraction technique. The new lattice parameters for the tetragonal lattice structure are: a0=9.990 × 10‐10 m and c0=12.264 × 10‐10 m, with a corresponding volume 1.224 × 10‐27 m3. The data provided by the Joint Committee on Powder Diffraction Standards are inconsistent both in lattice parameter values and Miller indices. The X‐ray powder diffraction pattern of BaAl2Ti5O14 was indexed using the LSUCR (least‐squares unit cell refinement) computer program.
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