Our understanding of the tectonic development of the African continent and the interplay between its geological provinces is hindered by unevenly distributed seismic instrumentation. In order to better understand the continent, we used long‐period ambient noise full‐waveform tomography on data collected from 186 broadband seismic stations throughout Africa and surrounding regions to better image the upper mantle structure. We extracted empirical Green's functions from ambient seismic noise using a frequency‐time normalization method and retrieved coherent signal at periods of 7–340 s. We simulated wave propagation through a heterogeneous Earth using a spherical finite‐difference approach to obtain synthetic waveforms, measured the misfit as phase delay between the data and synthetics, calculated numerical sensitivity kernels using the scattering integral approach, and iteratively inverted for structure. The resulting images of isotropic, shear wave speed for the continent reveal segmented, low‐velocity upper mantle beneath the highly magmatic northern and eastern sections of the East African Rift System (EARS). In the southern and western sections, high‐velocity upper mantle dominates, and distinct, low‐velocity anomalies are restricted to regions of current volcanism. At deeper depths, the southern and western EARS transition to low velocities. In addition to the EARS, several low‐velocity anomalies are scattered through the shallow upper mantle beneath Angola and North Africa, and some of these low‐velocity anomalies may be connected to a deeper feature. Distinct upper mantle high‐velocity anomalies are imaged throughout the continent and suggest multiple cratonic roots within the Congo region and possible cratonic roots within the Sahara Metacraton.

Crustal pathways connecting deep sources of melt and the active volcanoes they supply are poorly understood. Beneath Mounts St. Helens, Adams, and Rainier these pathways connect subduction-induced ascending melts to shallow magma reservoirs. Petrogenetic modeling predicts that when these melts are emplaced as a succession of sills into the lower crust they generate deep crustal hot zones. While these zones are increasingly recognized as a primary site for silicic differentiation at a range of volcanic settings globally, imaging them remains challenging. Near Mount Rainier, ascending melt has previously been imaged ~28 km northwest of the volcano, while to the south, the volcano lies on the margin of a broad conductive region in the deep crust. Using 3D full-waveform tomography, we reveal an expansive low-velocity zone, which we interpret as a possible hot zone, linking ascending melts and shallow reservoirs. This hot zone may supply evolved magmas to Mounts St. Helens and Adams, and possibly Rainier, and could contain approximately twice the melt volume as the total eruptive products of all three volcanoes combined. Hot zones like this may be the primary reservoirs for arc volcanism, influencing compositional variations and spatial-segmentation along the entire 1100 km-long Cascades Arc.

[1] New land and marine gravity data reveal two positive residual gravity anomalies in the Northern Hawaiian Islands: one over Kaua'i, the other between the islands of Kaua'i and Ni'ihau. These gravitational highs are similar in size and magnitude to those of other Hawaiian volcanoes, indicating local zones of high-density crust, attributed to olivine cumulates in solidified magma reservoirs. The residual gravity high over Kaua'i is located in the Līhu'e Basin, offset 8-12 km east of Kaua'i's geologically mapped caldera. This offset suggests that the mapped caldera is a collapsed feature later filled in with lava and not the long-term center of Kaua'i shield volcanism. A second residual gravity high, in the submarine channel between Kaua'i and Ni'ihau, marks the volcanic center of the Ni'ihau shield volcano. This second residual gravity anomaly implies that Ni'ihau's eastern boundary extended ∼20 km east of its present location. Through inversion, the residual gravity anomalies were modeled as being produced by two solidified magma reservoirs with average densities of 3100 kg/m 3 and volumes between 2470 and 2540 km 3 . Considering the locations and sizes of the residual gravity anomalies/magma reservoirs, the extent of the two islands' paleoshorelines and potassium-argon dating of shield-stage lavas, we conclude that the two islands were not connected subaerially during their respective shield stages and that Ni'ihau's topographic summit was removed by an eastern flank collapse between 4.3 and 5.6 Ma. Continued constructional volcanism on western Kaua'i likely covered much of the submerged remains of eastern Ni'ihau.

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[1] The Hawaiian Islands are the most geologically studied hot-spot islands in the world yet surprisingly, the only largescale compilation of marine and land gravity data is more than 45 years old. Early surveys served as reconnaissance studies only, and detailed analyses of the crustal-density structure have been limited. Here we present a new chainwide gravity compilation that incorporates historical island surveys, recently published work on the islands of Hawai'i, Kaua'i, and Ni'ihau, and >122,000 km of newly compiled marine gravity data. Positive residual gravity anomalies reflect dense intrusive bodies, allowing us to locate current and former volcanic centers, major rift zones, and a previously suggested volcano on Ka'ena Ridge. By inverting the residual gravity data, we generate a 3-D view of the dense, intrusive complexes and olivine-rich cumulate cores within individual volcanoes and rift zones. We find that the Hāna and Ka'ena ridges are underlain by particularly high-density intrusive material (>2.85 g/cm 3 ) not observed beneath other Hawaiian rift zones. Contrary to previous estimates, volcanoes along the chain are shown to be composed of a small proportion of intrusive material (<30% by volume), implying that the islands are predominately built extrusively.

The 2018 lower East Rift Zone eruption of Kīlauea (Hawai‘i) marked a dramatic change in the volcano’s 35-year-long rift zone eruption. The collapse of the middle East Rift Zone vent Pu‘u ‘Ō‘ō was followed by one of the volcano’s most voluminous eruptions in 500 years. Over the course of this 3-month eruption, the draining of summit-stored magma led to near-daily collapses of a portion of the caldera and ultimately up to 500 m of summit subsidence. While deformation data indicated that the summit and middle East Rift Zone were inflating for the previous several years, why Pu‘u ‘Ō‘ō collapsed and what initiated down-rift dike propagation remains unclear. Using ambient noise seismic interferometry, we show that a Ml5.3 decollement earthquake beneath Kīlauea’s south flank in June 2017 induced a coseismic decrease of up to 0.30% in seismic velocity throughout the volcano. This velocity decrease may have been caused by dynamic stress–induced shallow crustal fracture, i.e., weakening to dilatant crack growth, and was greatest near Pu‘u ‘Ō‘ō. Additionally, we verify a pre-eruptive increase in seismic velocity, consistent with increasing pressurization in the volcano’s shallow summit magma reservoir. This velocity increase occurred coincident with the first in a series of lower-crustal earthquake swarms, 6 days before a 2-month period of rapid summit and middle East Rift Zone inflation. The increase in up-rift magma-static pressure, combined with the pre-existing weakness from the June 2017 earthquake, may have facilitated down-rift dike propagation and the devastating 2018 eruption.

Water radiolysis continuously produces H2 and oxidized chemicals in wet sediment and rock. Radiolytic H2 has been identified as the primary electron donor (food) for microorganisms in continental aquifers kilometers below Earth’s surface. Radiolytic products may also be significant for sustaining life in subseafloor sediment and subsurface environments of other planets. However, the extent to which most subsurface ecosystems rely on radiolytic products has been poorly constrained, due to incomplete understanding of radiolytic chemical yields in natural environments. Here we show that all common marine sediment types catalyse radiolytic H2 production, amplifying yields by up to 27X relative to pure water. In electron equivalents, the global rate of radiolytic H2 production in marine sediment appears to be 1-2% of the global organic flux to the seafloor. However, most organic matter is consumed at or near the seafloor, whereas radiolytic H2 is produced at all sediment depths. Comparison of radiolytic H2 consumption rates to organic oxidation rates suggests that water radiolysis is the principal source of biologically accessible energy for microbial communities in marine sediment older than a few million years. Where water permeates similarly catalytic material on other worlds, life may also be sustained by water radiolysis.

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