was studied. With each of these pentafluorides a one-to-one complex is formed and characterized by X-ray powder diffraction patterns and vibrational spectra. The latter strongly support ionic structures. Both orbital valence and Urey-Bradley force fields were computed and evaluated for
Die Reaktion von ClOF3 mit den Pentafluoriden AFS (A: P, As, V, Sb, Ta, Nb, Bi) führt zu weißen, kristallinen 1:1‐Addukten, deren Schwingungsspektren auf ioninische Strukturen (I) schließen lassen.
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