During the operation of proton exchange membrane (PEM) fuel cells, a high-resistance oxide is often formed on the cathode surface of base metal bipolar plates. Over time, this corrosion mechanism leads to a drop in fuel cell efficiency and potentially to complete failure. To address this problem, we have developed alloys capable of forming oxides that are both conductive and chemically stable under PEM fuel cell operating conditions. Five alloys of titanium with tantalum or niobium were investigated. The oxides were formed on the alloys by cyclic voltammetry in solutions mimicking the cathode- and anode-side environment of a PEM fuel cell. The oxides of all tested alloys had lower surface resistance than the oxide of pure titanium. We also investigated the chemical durability of Ti–Nb and Ti–Ta alloys in more concentrated solutions beyond those typically found in PEM fuel cells. The oxide films formed on Ti–Nb and Ti–Ta alloys remained conductive and chemically stable in these concentrated solutions. The stability of the oxide films was evaluated; Ti alloys having 3% Ta and Nb were identified as potential candidates for bipolar plate materials.
Purpose
This paper aims to artificially generate seismic accelerograms compatible with the response spectrum imposed as a function of the given environmental parameters such as magnitude, epicentral distance and type of soil. This study is necessary for the non-linear dynamic analysis of structures in regions where real seismic records are not available.
Design/methodology/approach
First, a stochastic iterative method is used to estimate the spectral densities of acceleration power from the respective target response spectra. Thereafter, based on the superposition of seismic waves, a subsequent iterative procedure, which implicitly takes into account the non-stationary character of temporal intensity content of strong ground motions, is developed to synthesize, from these power spectral density, the corresponding acceleration time histories. The phase contents of the ground acceleration samples, thus obtained, are generated using a probability density function of phase derivatives with characteristic parameters estimated from seismological considerations. When based on seismic codes spectrum compatible criteria, this procedure can be used to generate strong ground motions for structural design.
Findings
The results found show that the forms of acceleration of the target and the simulated signals have similar characteristics in terms of strong motion durations, the peak ground acceleration values, corresponding time of occurrence and also, the corresponding cumulative energy functions follow practically the same pattern of variations.
Originality/value
The aim of this study is to generate seismic accelerograms compatible with regulatory spectra by the composition of the three acceleration duration segments based on environmental parameters (magnitude, epicentral distance and type of soil) and which subsequently serves to control the time envelope of the generated signals, and therefore the random generation of phase derivatives, which has not been previously treated.
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