Under the ANDRA Meuse/Haute Marne underground research laboratory scientific programme, two boreholes (EST204 and EST205) were drilled to a depth of 510 m for the purposes of scientific characterization. Twenty-nine core samples were taken in borehole EST205 every 3 m between 422 and 504 m depth. Physical property measurements (water content, porosity, density, specific surface), geochemical analyses (major and trace

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Abstract--The validity of the saddle/001 method for estimating the percentage of smectite layers in randomly interstratified illite/smectite (US) minerals as a routine laboratory technique has been examined with respect to the effects of the crystallite size distribution (N = number of layers) of I/S and the degree of preferred orientation of crystallites in the prepared specimen. X-ray powder diffraction experiments of I/S clays indicated that the crystallite size distribution was 3 < N < 12; these values were supported satisfactorily by the variation of the d(002) value of the samples. An analysis of the Lorentz factor concerning the degree of preferred orientation of crystallites indicated that a calibration curve calculated using the random powder Lorentz factor and the above crystallite size distribution fit the data better than an assumption of perfect orientation. Consequently, if a calibration curve of the saddle/001 ratio is used to estimate the percentage of smectite layers in I/S, an error of 10-15% should be expected from the variable crystallite size distribution of actual samples, in which I/S dominates over other phyllosilicate phases that give reflection between 10-14 A. This method is useful, however, in estimating the relative percentage of smectite layers in randomly interstratified US for samples examined under identical experimental conditions.

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