The radiogenic isotopic compositions of inorganic heavy elements such as Sr, Nd, and Pb of the food chain may constitute a reliable geographic fingerprint, their isotopic ratios being inherited by the geological substratum of the territory of production. The Sr isotope composition of geomaterials (i.e., rocks and soils) is largely variable, and it depends upon the age of the rocks and their nature (e.g., genesis, composition). In this study we developed a high-precision analytical procedure for determining Sr isotopes in wines at comparable uncertainty levels of geological data. With the aim of verifying the possibility of using Sr isotope in wine as a reliable tracer for geographic provenance, we performed Sr isotope analyses of 45 bottled wines from four different geographical localities of the Italian peninsula. Their Sr isotope composition has been compared with that of rocks from the substrata (i.e., rocks) of their vineyards. In addition wines from the same winemaker but different vintage years have been analyzed to verify the constancy with time of the (87)Sr/(86)Sr. Sr isotope compositions have been determined by solid source thermal ionization mass spectrometry following purification of Sr in a clean laboratory. (87)Sr/(86)Sr of the analyzed wines is correlated with the isotopic values of the geological substratum of the vineyards, showing little or no variation within the same vineyard and among different vintages. Large (87)Sr/(86)Sr variation is observed among wines from the different geographical areas, reinforcing the link with the geological substratum of the production territory. This makes Sr isotopes a robust geochemical tool for tracing the geographic authenticity and provenance of wine.
The increase in the world wine market has required continued improvements in viticultural zoning in both old and young production regions. The many proposed zoning methods vary according to the study area in which they are applied as well as to the perspective of the authors. Thus, there is little agreement on which factors (climate, landscape, geology, soil and human intervention) should be taken into account. The aim of this work is to provide a methodology to optimize and possibly increase the development of wine production regions, identifying the zones with different potential suitability. We coupled the computation of bioclimatic indices based on Geoviticulture Multicriteria Climatic Classification System with a GIS (geographic information system) analysis based on the integration of easily accessible geological, morphometric and geomorphological data, in addition to viticulture land use. The final result of this methodology is a suitability map distinguishing sectors of different suitability for wine production in a vine cropping area. We tested the methodology on the Cesanese DOC (Denomination of Origin Verified) zone (Latium, central Italy). The resulting suitability map indicates that the areas more favourable for viticulture are only partially exploited, encouraging the possibility of increasing the production of high-quality wine in the Cesanese DOC area. This result underlines the applicability of our methodology in land-use planning and management
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