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The escape rate from the zero voltage state in a superconducting Josephson junction (JJ) is determined by the temperature, but it saturates at low temperature due to macroscopic quantum tunneling (MQT). Complications due to d-wave symmetry in a high temperature superconductor, like low energy quasiparticles and an unconventional current-phase relation, may influence the escape rate. We report, for the first time to our knowledge, the observation of MQT in a YBa(2)Cu(3)O(7-delta) grain boundary biepitaxial JJ. This proves that dissipation can be significantly reduced by a proper junction configuration, which is of significance for quantum coherence.

We have measured the angular dependence of the Josephson critical current density (J(C)) in c-axis tilt biepitaxial grain boundary YBa(2)Cu(3)O(7-delta) junctions. We observe for the first time intrinsic d-wave pairing symmetry effects manifested as an oscillatory dependence of J(C) on angle. This intrinsic effect is evident even though spontaneous currents, possibly induced by faceting or barrier impurities, are observed in the grain boundaries.