Modification of alloys, in particular, by calcium and barium, is one of the promising directions for obtaining alloys with a fine crystalline structure. Complex ferroalloys – ferroalumosilicocalcium and ferrosilicobarium – were developed in the Chemical and Metallurgical Institute after Zh. Abishev. It was shown, that modification of steel by silicon-aluminum complex alloys containing chemically active elements – calcium and barium, should become one of the most effective methods to improve the quality of machine-building metal products.The chemical compositions of the smelted ferroaluminosiliconcalcium and ferrosilicobarium presented. The melting range of the nonmetallic compound formed during the deoxidation of steel by complex alloy containing calcium determined. Results of mechanical tests of the specimens of steel, modified by a complex alloy containing barium considered. A comparison of microstructure of the current production route steel and deoxidized with the complex alloys was carried out.In the course of metallographic studies of experimental steel specimens, a modifying influence on the morphology of nonmetallic inclusions by calcium and barium, supplied in a complex with aluminum and silicon alloys, was established.Metal processing by complex alloys such as ferrosilicoaluminum with calcium (FASC) and ferrosilicobarium (FSAB) indicates the possibility of achieving a higher degree of refining from oxide nonmetallic inclusions and a more even distribution of them in the ingot.The results of the industrial heats also indicated a possibility of improving of quality of casting through the decreasing of hot thermal cracks and gas-shrinkage defects, cleaner grain boundaries, a significant reduction in the number and size of carbide inclusions.
In the article there are presented results of a research that was carried out to determine a reason for the increase of more than 1,22 g/cm3 coal-tar oil density at the coke production of “ArcelorMittal Temirtau” joint-stock company. There have been studied samples of coal concentrates from nine layers of eight mines in Karaganda coal basin and GZh coal concentrate which are supplied to the coke chemical production of “ArcelorMittal Temirtau” joint-stock company from “Kunetskaya” Enrichment plant (Russia). During the work there has been determined dependence of the gas composition on the temperature affecting gas that was released during coal carbonizing process. It is experimentally established that with an increase in the temperature of the released coke gas above 750 ° C to 1000 ° C, light fractions evaporate from the resin and are removed into the gas discharge path, which is accompanied by a weighting, an increase in the density captured for processing coal tar into pitch. The results of the resin studies that is isolated in the same temperature ranges show the indicators of the resin yield and its density during the tests of concentrates also follow a certain pattern – with an increase in the coal carbonizing temperature and with overheating of the released gas, the resin density increases and its yield decreases. The researches in the plant has found that the technological reason for the weighting of the coke gas resin is a low level of coal charge stockline, which makes possible to linger the coke gas in the underroof space and to overheat with increasing the access of light fractions of the resin with the gas.
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