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The need for environmental friendly and energy efficient building design has stimulated the design of new facade technologies, including various configurations of double skin facades. This paper investigates the thermal performance of a ventilated wall, both for heating and cooling. A thermal analysis was carried out, paying special attention to the characterization of the heat convection resulting from the buoyancy–induced flow in the open air channel which proved to be a critical aspect of the ventilated wall's behaviour. An integrated thermal and air flow model for the entire system was developed. A model of the ventilated wall construction was developed with the ESP-r simulation program and checked against experimental data from a real-scale test cell facility. The thermal benefits of adding a radiant barrier layer were also investigated. The results showed that this layer was beneficial in terms of the energy performance of the construction. Also, the comparison between the experimental and simulation model results showed satisfactory levels of convergence with the exception of the night hours during the summer period. A sensitivity analysis was also undertaken in order to investigate the main factors and the extent of their effect on the temperature variation inside the ventilated facades