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Quinazoliw isothioeyanate 1 reads with various nudeophiks (nitroafford heterocyclic spstemg 2-13. Also, tbe [4+ 21 cyddtion dnnamic sdd derivatives gave novel heterocyclic ompomds 14-16. Moreover, the reactioll of 1 with active methylene ompomds d r Michael reactioo anxiitioos a h ms investigated to yield 17 and 18 and it wsf f d that all these d o m pruceeded via isothiocyanste heterocyclization to furnish non-condensed heterocyclic for their e n t i m i d i activities. p l mrleophiles, oxygen rmdeophiies and sulphur rmdeophiles) to reactionof1 with phenyl isocyaoate, bemylidew alyl amine and compounds. someofthenewlysynthesizedcompaundswen?tested Keywords timicrobial activity quitlszoline congeners, quinazoline isothiccyanate, an-

A new series of anionic surfactants with dual type of activity antimicrobial and surface activity have been synthesized by reaction of 4H‐3,1‐benzoxazinone 3 and quinazolinethione 10 with nitrogen nucleophiles and activated olefinic compounds. The compounds were evaluated for their surface activity as well as their antimicrobial and biodegradability properties.

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The widespread use of GPS-enabled smartphones along with the popularity of micro-blogging and social networking applications, e.g., Twitter and Facebook, has resulted in the generation of huge streams of geo-tagged textual data. Many applications require real-time processing of these streams. For example, location-based e-coupon and ad-targeting systems enable advertisers to register millions of ads to millions of users. The number of users is typically very high and they are continuously moving, and the ads change frequently as well. Hence sending the right ad to the matching users is very challenging. Existing streaming systems are either centralized or are not spatial-keyword aware, and cannot efficiently support the processing of rapidly arriving spatial-keyword data streams. This paper presents Tornado, a distributed spatial-keyword stream processing system. Tornado features routing units to fairly distribute the workload, and furthermore, co-locate the data objects and the corresponding queries at the same processing units. The routing units use the Augmented-Grid, a novel structure that is equipped with an efficient search algorithm for distributing the data objects and queries. Tornado uses evaluators to process the data objects against the queries. The routing units minimize the redundant communication by not sending data updates for processing when these updates do not match any query. By applying dynamically evaluated cost formulae that continuously represent the processing overhead at each evaluator, Tornado is adaptive to changes in the workload. Extensive experimental evaluation using spatio-textual range queries over real Twitter data indicates that Tornado outperforms the nonspatio-textually aware approaches by up to two orders of magnitude in terms of the overall system throughput.

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