下缘含有杂原子杯[4]芳烃的合成 及其阳离子选择性

Wang, Hao; 李喆,; 刘育,

doi:10.1360/zb2007-37-4-350

Cited by 2 publications

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“…长期以来, 对杯芳烃和柱芳烃功能化的研究主要集中在与苯环直接相连的取代基结构上 [2] , 如通过对苯环的上下边缘进行酰化和烷基化等反应, 从而构造出各种各样的衍生物. 这些化合物通过新的基团获得其他额外的性能, 能够与特定的客体产生主客体自组装效应 [3] , 从而被广泛应用于药物递送中的示踪 [4,5] , 功能纳米材料 [6] , 目标分子的捕获、存储和分离 [7,8] 异构体 [10] . 就杯 [4]芳烃而言, 这四种异构体分别为 rccc、rcct、rctt和rctc型(如果其中三个桥梁取代基与第一个空间位置相同, 即为全顺式异构体rccc).…”

Section: 大环化学是20世纪60年代以来兴起的一门交叉边unclassified

<italic>Meso</italic> position functionalized calix[<italic>n</italic>]arenes and pillar[<italic>n</italic>]arenes and their applications

Zhang¹,

Zuo²,

Wang³

et al. 2020

Sci. Sin.-Chim

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With the rapid development of macrocyclic chemistry, the functionalization of calix[n]arenes, pillar[n]arenes and other methylene linked macrocycles at their meso positions has drawn much attention. These modified macrocyclic derivatives have new functions on the basis of not changing their original properties. Not only more functional groups can be introduced, but also their applications, such as drug delivery, chemical detection, fluorescent system fabrication, are further improved due to the self-assembly behavior of host and guest. Based on the comprehensive analysis of the current research on the modification of calix[n]arenes and pillar[n]arenes at meso position, this review systematically summarizes the modification methods, the changes of the modified structures, and applications. The opportunities and challenges of its future development have been discussed.

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Section: 大环化学是20世纪60年代以来兴起的一门交叉边unclassified

<italic>Meso</italic> position functionalized calix[<italic>n</italic>]arenes and pillar[<italic>n</italic>]arenes and their applications

Zhang¹,

Zuo²,

Wang³

et al. 2020

Sci. Sin.-Chim

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Multi-reference configuration interaction of the ground and low-lying excited states of LiC

Wang¹,

Chen²,

Cheng³

et al. 2010

Acta Phys. Sin.

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The potential energy curves (PECs) for the ground electronic state X4Σ-and five low-lying excited electronic states (a2Π, b2Δ, c2Σ-, d2Σ+, A4Π) of LiC have been calculated using the multiconfiguration reference configuration interaction method including Davidson correction (MRCI+Q). And PECs were fitted to analytical Murrell-Sorbie potential function to deduce the spectroscopic parameters of equilibrium bond length Re, rotation coupling constant ωe, anharmonic constant ωeχe, equilibrium rotation constant Be and vibration-rotation coupling constant αe. Those values were also compared with the other results currently available. By solving the radial Schrdinger equation of nuclear motion, the vibration levels, inertial rotation constant and six centrifugal distortion constants (Dν, Hν, Lν, Mν,Nν,and Oν) are reported for the first time.

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下缘含有杂原子杯[4]芳烃的合成及其阳离子选择性

Cited by 2 publications

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<italic>Meso</italic> position functionalized calix[<italic>n</italic>]arenes and pillar[<italic>n</italic>]arenes and their applications

<italic>Meso</italic> position functionalized calix[<italic>n</italic>]arenes and pillar[<italic>n</italic>]arenes and their applications

Multi-reference configuration interaction of the ground and low-lying excited states of LiC

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下缘含有杂原子杯[4]芳烃的合成 及其阳离子选择性

Cited by 2 publications

References 0 publications

&lt;italic&gt;Meso&lt;/italic&gt; position functionalized calix[&lt;italic&gt;n&lt;/italic&gt;]arenes and pillar[&lt;italic&gt;n&lt;/italic&gt;]arenes and their applications

&lt;italic&gt;Meso&lt;/italic&gt; position functionalized calix[&lt;italic&gt;n&lt;/italic&gt;]arenes and pillar[&lt;italic&gt;n&lt;/italic&gt;]arenes and their applications

Multi-reference configuration interaction of the ground and low-lying excited states of LiC

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下缘含有杂原子杯[4]芳烃的合成及其阳离子选择性

<italic>Meso</italic> position functionalized calix[<italic>n</italic>]arenes and pillar[<italic>n</italic>]arenes and their applications

<italic>Meso</italic> position functionalized calix[<italic>n</italic>]arenes and pillar[<italic>n</italic>]arenes and their applications